Catalysis Today

, том 183 , издание 1 , страницы 72-78

Structure sensitivity in the hydrogenation of unsaturated hydrocarbons over Rh nanoparticles

Тип публикации: Journal Article

Дата публикации: 2012-03-01

Elsevier

Catalysis Today

scimago Q1

wos Q1

БС1

SJR: 1.05

CiteScore: 11.2

Impact factor: 5.3

ISSN: 09205861, 18734308

DOI: 10.1016/j.cattod.2011.10.014

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General Chemistry

Catalysis

Краткое описание

A series of Rh nanoparticles with sizes between 3.5 and 11.4 nm were synthesized in the presence of polyvinylpyrrolidone and evaluated for their performance as catalysts in the hydrogenation of phenylacetylene and 1-octene. The reaction is zeroth order in the reactant for phenylacetylene and 1-octene. The catalytic activity increased with Rh particle size in the hydrogenation of phenylacetylene, whereas the activity in 1-octene hydrogenation did not depend on particle size. The possible explanations for this different particle size behavior are discussed.

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Quek X. Y., Guan Y., Hensen E. J. Structure sensitivity in the hydrogenation of unsaturated hydrocarbons over Rh nanoparticles // Catalysis Today. 2012. Vol. 183. No. 1. pp. 72-78.

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Quek X. Y., Guan Y., Hensen E. J. Structure sensitivity in the hydrogenation of unsaturated hydrocarbons over Rh nanoparticles // Catalysis Today. 2012. Vol. 183. No. 1. pp. 72-78.

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TY - JOUR

DO - 10.1016/j.cattod.2011.10.014

UR - https://doi.org/10.1016/j.cattod.2011.10.014

TI - Structure sensitivity in the hydrogenation of unsaturated hydrocarbons over Rh nanoparticles

T2 - Catalysis Today

AU - Quek, Xian Yang

AU - Guan, Yejun

AU - Hensen, Emiel J.M.

PY - 2012

DA - 2012/03/01

PB - Elsevier

SP - 72-78

IS - 1

VL - 183

SN - 0920-5861

SN - 1873-4308

ER -

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@article{2012_Quek,

author = {Xian Yang Quek and Yejun Guan and Emiel J.M. Hensen},

title = {Structure sensitivity in the hydrogenation of unsaturated hydrocarbons over Rh nanoparticles},

journal = {Catalysis Today},

year = {2012},

volume = {183},

publisher = {Elsevier},

month = {mar},

url = {https://doi.org/10.1016/j.cattod.2011.10.014},

number = {1},

pages = {72--78},

doi = {10.1016/j.cattod.2011.10.014}

}

MLA

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MLA Скопировать

Quek, Xian Yang, et al. “Structure sensitivity in the hydrogenation of unsaturated hydrocarbons over Rh nanoparticles.” Catalysis Today, vol. 183, no. 1, Mar. 2012, pp. 72-78. https://doi.org/10.1016/j.cattod.2011.10.014.

Издатель

Elsevier

Журнал

Catalysis Today

scimago Q1

wos Q1

БС1

SJR

1.05

CiteScore

11.2

Impact factor

5.3

ISSN

09205861 (Print)

18734308