Catalysis Today, volume 281, pages 379-386
Synthesis of acrylates from olefins and CO2 using sodium alkoxides as bases
1
Catalysis Research Laboratory (CaRLa), Im Neuenheimer Feld 584, 69120 Heidelberg, Germany
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2
Synthesis and Homogeneous Catalysis, BASF SE Carl-Bosch-Str. 38 67056 Ludwigshafen Germany
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3
Organisch-Chemisches Institut
5
69120 Heidelberg Germany
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6
Synthesis and Homogeneous Catalysis, BASF SE
7
Carl-Bosch-Str. 38 67056 Ludwigshafen Germany
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Publication type: Journal Article
Publication date: 2017-03-01
General Chemistry
Catalysis
Abstract
We have discovered a simple procedure for an industrially applicable alternative synthesis of sodium acrylate via the catalytic carboxylation of ethylene with CO 2 . We identified tert -butoxide as suitable base in this catalytic transformation, which was excluded in previous reports, based on investigations on the stability of the corresponding carbonates. In addition, we were able to access a completely zinc-free procedure for the sodium acrylate formation by introducing a regeneration step during the catalyst recycle. Due to the basicity of the sodium tert -butoxide, it was also possible to carboxylate different terminal and internal olefins, which could not be achieved using the previously reported nickel system using phenolate bases.
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Manzini S. et al. Synthesis of acrylates from olefins and CO2 using sodium alkoxides as bases // Catalysis Today. 2017. Vol. 281. pp. 379-386.
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Manzini S., Huguet N., Trapp O., Paciello R. A., Schaub T. Synthesis of acrylates from olefins and CO2 using sodium alkoxides as bases // Catalysis Today. 2017. Vol. 281. pp. 379-386.
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TY - JOUR
DO - 10.1016/j.cattod.2016.03.025
UR - https://doi.org/10.1016/j.cattod.2016.03.025
TI - Synthesis of acrylates from olefins and CO2 using sodium alkoxides as bases
T2 - Catalysis Today
AU - Manzini, Simone
AU - Huguet, Núria
AU - Trapp, Oliver
AU - Paciello, Rocco A
AU - Schaub, Thomas
PY - 2017
DA - 2017/03/01
PB - Elsevier
SP - 379-386
VL - 281
SN - 0920-5861
ER -
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@article{2017_Manzini,
author = {Simone Manzini and Núria Huguet and Oliver Trapp and Rocco A Paciello and Thomas Schaub},
title = {Synthesis of acrylates from olefins and CO2 using sodium alkoxides as bases},
journal = {Catalysis Today},
year = {2017},
volume = {281},
publisher = {Elsevier},
month = {mar},
url = {https://doi.org/10.1016/j.cattod.2016.03.025},
pages = {379--386},
doi = {10.1016/j.cattod.2016.03.025}
}