Catalysis Today

, volume 301 , pages 258-265

The effect of preparation conditions of Pd/C catalyst on its activity and selectivity in the aqueous-phase hydrogenation of 2,4,6-trinitrobenzoic acid

Olga B Belskaya ^{1, 2}

Roman Mironenko ^{1, 3}

Valentin P Talsi ¹

Vladimir A Rodionov ¹

Tatyana I Gulyaeva ¹

Sergey V Sysolyatin ⁴

Vladimir A. Likholobov ^{2, 5}

Hide authors affiliations Show authors affiliations: 5 affiliations

Institute of Hydrocarbons Processing, Siberian Branch of the Russian Academy of Sciences, 54 Neftezavodskaya st., 644040, Omsk, Russia |

Omsk State Technical University, 11 Mira ave., 644050, Omsk, Russia |

Dostoevsky Omsk State University, 55a Mira ave., 644077, Omsk, Russia |

⁴

Institute for Problems of Chemical and Energetic Technologies, Siberian Branch of the Russian Academy of Sciences, 1 Socialisticheskaya st., 659322, Biysk, Altai krai, Russia |

⁵

Omsk Scientific Center, Siberian Branch of the Russian Academy of Sciences, 15 Marksa ave., 644024, Omsk, Russia |

Publication type: Journal Article

Publication date: 2018-03-01

Elsevier

Catalysis Today

scimago Q1

wos Q1

SJR: 1.050

CiteScore: 11.2

Impact factor: 5.3

ISSN: 09205861, 18734308

DOI: 10.1016/j.cattod.2017.02.037

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General Chemistry

Catalysis

Abstract

The effect of the nature of alkaline agent and pH value of hydrolysis of Pd(II) chloride complex into palladium polynuclear hydroxo complexes, as precursor of active component in Pd/C catalyst, on the dispersion of palladium particles supported on carbon material Sibunit was revealed. It was shown that an increase in the particle size of supported palladium enhances the specific catalytic activity in hydrogenation of 2,4,6-trinitrobenzoic acid and changes the direction of the transformation (increases the fraction of non-aromatic intermediate, cyclohexane-1,3,5-trione trioxime, in the products). The results obtained are essential for optimizing the particle size of supported palladium in selective hydrogenation of polyfunctional organic compounds.

Found

2 citations

Redina Elena

🥼 🤝

PhD in Chemistry

43 publications, 618 citations, 46 reviews

h-index: 14

N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

Research interests

Green chemistry

Heterogeneous catalysis

Nanoparticles of metal oxides

Organic synthesis

1 citation

Kuriganova Aleksandra

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DSc in Engineering

47 publications, 629 citations, 2 reviews

h-index: 15

Platov South-Russian State Polytechnic University (NPI)

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Belskaya O. B. et al. The effect of preparation conditions of Pd/C catalyst on its activity and selectivity in the aqueous-phase hydrogenation of 2,4,6-trinitrobenzoic acid // Catalysis Today. 2018. Vol. 301. pp. 258-265.

GOST all authors (up to 50) Copy

Belskaya O. B., Mironenko R., Talsi V. P., Rodionov V. A., Gulyaeva T. I., Sysolyatin S. V., Likholobov V. A. The effect of preparation conditions of Pd/C catalyst on its activity and selectivity in the aqueous-phase hydrogenation of 2,4,6-trinitrobenzoic acid // Catalysis Today. 2018. Vol. 301. pp. 258-265.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1016/j.cattod.2017.02.037

UR - https://doi.org/10.1016/j.cattod.2017.02.037

TI - The effect of preparation conditions of Pd/C catalyst on its activity and selectivity in the aqueous-phase hydrogenation of 2,4,6-trinitrobenzoic acid

T2 - Catalysis Today

AU - Belskaya, Olga B

AU - Mironenko, Roman

AU - Talsi, Valentin P

AU - Rodionov, Vladimir A

AU - Gulyaeva, Tatyana I

AU - Sysolyatin, Sergey V

AU - Likholobov, Vladimir A.

PY - 2018

DA - 2018/03/01

PB - Elsevier

SP - 258-265

VL - 301

SN - 0920-5861

SN - 1873-4308

ER -

BibTex

Cite this

BibTex (up to 50 authors) Copy

@article{2018_Belskaya,

author = {Olga B Belskaya and Roman Mironenko and Valentin P Talsi and Vladimir A Rodionov and Tatyana I Gulyaeva and Sergey V Sysolyatin and Vladimir A. Likholobov},

title = {The effect of preparation conditions of Pd/C catalyst on its activity and selectivity in the aqueous-phase hydrogenation of 2,4,6-trinitrobenzoic acid},

journal = {Catalysis Today},

year = {2018},

volume = {301},

publisher = {Elsevier},

month = {mar},

url = {https://doi.org/10.1016/j.cattod.2017.02.037},

pages = {258--265},

doi = {10.1016/j.cattod.2017.02.037}

}

Publisher

Elsevier

Journal

Catalysis Today

scimago Q1

wos Q1

SJR

1.050

CiteScore

11.2

Impact factor

5.3

ISSN

09205861 (Print)

18734308

Profiles

Roman M Mironenko