The role of the compositions of HZSM-5 zeolites modified with nanosized anatase in propane and ethanol conversion

For the first time catalytic systems based on HZSM-5 zeolites (Si/Al=12, 25, 40) with nanosized anatase (NA) were obtained in situ by a modified hydrothermal method and a sol-gel method. Initial HZSM-5 and NA/HZSM-5 were characterized (XRPD, XAS, FT-IR, DSC, BET, XPS, SEM, TPD) and analyzed in the reactions of propane (liquefied petroleum gas) conversion ( РС ; temperature range 200–870 °С) with the formation of the main products propylene (C 3 H 6 , PP ) and ethylene (C 2 H 4 , ETH ) and liquid ethanol conversion ( EC ; temperature range 150–360 °C) with the formation of diethyl ether ((C 2 H 5 ) 2 O, DEE ) and ETH . In the PC reaction the maximum selectivity (S ETH = 75%) and conversion (α P = 65%) were obtained on HZSM-5(40) (650 °С). With an increase in the NA content in NA/HZSM-5 S ETH value increases up to 85%. In the EC reaction S DEE/ETH ~98–99% was reached on HZSM-5(25) (200 °C) and HZSM-5(40) (300 °C); the α E to ETH is comparable (94%) for all HZSM-5 (300 °C). Modification of HZSM-5 with NA leads to a shift in the EC reaction temperature to lower temperature region (α E to ETH ~98% at 280 °C) with S DEE/ETH ~94–100% for NA/HZSM-5(25) and NA/HZSM-5(12) obtained by a modified hydrothermal method. It was established the relationship between HZSM-5 and NA/HZSM-5 catalytic activity and their characteristics: Si/Al, NA content and Ti coordination number (NA/HZSM-5), the content of "zeolite water" with OH groups, specific surface area, meso- and micropores volume and spherical particles size (HZSM-5), surface energy of adsorption centers (HZSM-5 and NA/HZSM-5), and hence the content of acid sites, the strength of which is also determined by the temperature of the catalytic reaction. The reaction mechanisms have been presented. The obtained NA/HZSM-5 catalysts have a higher or comparable catalytic activity to commercial ones, but low cost, ease of preparation, and versatility. • Catalysts HZSM-5/nanosized anatase (NA) were obtained in situ by two methods. • Relationship between catalysts characteristics and catalytic activity was established. • NA/HZSM-5 (sol-gel method) show higher catalytic activity in propane conversion. • NA/HZSM-5 (hydrothermal method) show higher catalytic activity in ethanol conversion.