Chinese Chemical Letters, volume 18, issue 7, pages 887-890
Highly active double metal cyanide complexes: Effect of central metal and ligand on reaction of epoxide/CO2
Publication type: Journal Article
Publication date: 2007-07-01
Journal:
Chinese Chemical Letters
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 9.1
ISSN: 10018417
General Chemistry
Abstract
Various novel double metal cyanide (DMC) catalysts were successfully prepared by modifying the central metal (M) and one of cyanide ion (CN−) in Zna[M(CN)b]c complex. Such modifications have significant impact on the catalytic efficiency as well as the polymer selectivity for the reaction of PO/CO2. Zn–Ni(II) DMC is a potential catalyst for alternating copolymerization of PO/CO2, and DMC catalysts based on Zn3[Co(CN)5X]2 (X = Br− and N3−) exhibit moderate efficiency for the production of polycarbonates. This research presents the preliminary exploration of novel DMC complex via chemical modification of its central metal and ligand.
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Citations by publishers
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1 publication, 2.08%
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1 publication, 2.08%
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Zhang X. et al. Highly active double metal cyanide complexes: Effect of central metal and ligand on reaction of epoxide/CO2 // Chinese Chemical Letters. 2007. Vol. 18. No. 7. pp. 887-890.
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Zhang X., Chen S. C., Wu X., Sun X. K., Liu F., Qi G. Highly active double metal cyanide complexes: Effect of central metal and ligand on reaction of epoxide/CO2 // Chinese Chemical Letters. 2007. Vol. 18. No. 7. pp. 887-890.
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TY - JOUR
DO - 10.1016/j.cclet.2007.05.017
UR - https://doi.org/10.1016/j.cclet.2007.05.017
TI - Highly active double metal cyanide complexes: Effect of central metal and ligand on reaction of epoxide/CO2
T2 - Chinese Chemical Letters
AU - Zhang, Xing-Hong
AU - Chen, Shang Chi
AU - Wu, Xian-Liang
AU - Sun, Xue Ke
AU - Liu, Fei
AU - Qi, Guo-rong
PY - 2007
DA - 2007/07/01 00:00:00
PB - Elsevier
SP - 887-890
IS - 7
VL - 18
SN - 1001-8417
ER -
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@article{2007_Zhang,
author = {Xing-Hong Zhang and Shang Chi Chen and Xian-Liang Wu and Xue Ke Sun and Fei Liu and Guo-rong Qi},
title = {Highly active double metal cyanide complexes: Effect of central metal and ligand on reaction of epoxide/CO2},
journal = {Chinese Chemical Letters},
year = {2007},
volume = {18},
publisher = {Elsevier},
month = {jul},
url = {https://doi.org/10.1016/j.cclet.2007.05.017},
number = {7},
pages = {887--890},
doi = {10.1016/j.cclet.2007.05.017}
}
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MLA
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Zhang, Xing-Hong, et al. “Highly active double metal cyanide complexes: Effect of central metal and ligand on reaction of epoxide/CO2.” Chinese Chemical Letters, vol. 18, no. 7, Jul. 2007, pp. 887-890. https://doi.org/10.1016/j.cclet.2007.05.017.