Elsevier
Chinese Chemical Letters
,  том 30 ,  издание 2 ,  страницы 473-476

Anionic polymerization initiated by lithium amides for preparing high molecular weight polyacrylonitrile

Тип публикации: Journal Article
Дата публикации: 2019-02-01
Elsevier
scimago Q1
wos Q1
БС1
SJR: 1.677
CiteScore: 15.7
Impact factor: 8.9
ISSN: 10018417, 18785964
General Chemistry
Краткое описание
Lithium amides have been proved to be effective anionic initiators for the anionic polymerization of acrylonitrile to get high molecular weight polyacrylonitrile in this study. Polyacrylonitrile with weight-average molecular weight ranging from 1.02 × 106 g/mol to 1.23 × 106 g/mol (Mw/Mn = 1.9–2.2) could be prepared utilizing lithium amides derived from diisopropylamine, diethylamine, hexamethyldisilazane, dicyclohexylamine, and 2,2,6,6-tetramethylpiperidine as initiators. The polymerization of acrylonitrile proceeded in a homogeneous manner in N,N-dimethylformamide and insignificant contribution of side reactions was confirmed.
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Shi X., Jiang J. Anionic polymerization initiated by lithium amides for preparing high molecular weight polyacrylonitrile // Chinese Chemical Letters. 2019. Vol. 30. No. 2. pp. 473-476.
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Shi X., Jiang J. Anionic polymerization initiated by lithium amides for preparing high molecular weight polyacrylonitrile // Chinese Chemical Letters. 2019. Vol. 30. No. 2. pp. 473-476.
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TY - JOUR
DO - 10.1016/j.cclet.2018.01.040
UR - https://doi.org/10.1016/j.cclet.2018.01.040
TI - Anionic polymerization initiated by lithium amides for preparing high molecular weight polyacrylonitrile
T2 - Chinese Chemical Letters
AU - Shi, Xiaolin
AU - Jiang, Jingyang
PY - 2019
DA - 2019/02/01
PB - Elsevier
SP - 473-476
IS - 2
VL - 30
SN - 1001-8417
SN - 1878-5964
ER -
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@article{2019_Shi,
author = {Xiaolin Shi and Jingyang Jiang},
title = {Anionic polymerization initiated by lithium amides for preparing high molecular weight polyacrylonitrile},
journal = {Chinese Chemical Letters},
year = {2019},
volume = {30},
publisher = {Elsevier},
month = {feb},
url = {https://doi.org/10.1016/j.cclet.2018.01.040},
number = {2},
pages = {473--476},
doi = {10.1016/j.cclet.2018.01.040}
}
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Shi, Xiaolin, and Jingyang Jiang. “Anionic polymerization initiated by lithium amides for preparing high molecular weight polyacrylonitrile.” Chinese Chemical Letters, vol. 30, no. 2, Feb. 2019, pp. 473-476. https://doi.org/10.1016/j.cclet.2018.01.040.