The anions and dianions of group 14 metalloles
Тип публикации: Journal Article
Дата публикации: 2005-04-01
scimago Q1
wos Q1
БС1
SJR: 4.638
CiteScore: 38.2
Impact factor: 23.5
ISSN: 00108545, 18733840
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Краткое описание
The synthesis, structures, and physical and chemical properties of mono- and dianions of group 14 metalloles (1-metallacyclopentadiene), heavier congeners of the cyclopentadienyl anion, are described. Dianions of metalloles have a substantial aromatic character owing to strong participation of divalent resonance forms and the silole anion shows different degrees of aromaticity depending on the substituent, but there is no evidence for aromaticity in the germole anion. Dianions of benzannulated metalloles have more aromatic character in the metallole ring than in the benzene ring. The synthesis and characterization of η5-silolyl and η5-germolyl metal complexes, analogs of ferrocene, and their unique reactivity are also described.
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Saito M., Yoshioka M. The anions and dianions of group 14 metalloles // Coordination Chemistry Reviews. 2005. Vol. 249. No. 7-8. pp. 765-780.
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Saito M., Yoshioka M. The anions and dianions of group 14 metalloles // Coordination Chemistry Reviews. 2005. Vol. 249. No. 7-8. pp. 765-780.
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TY - JOUR
DO - 10.1016/j.ccr.2004.08.004
UR - https://doi.org/10.1016/j.ccr.2004.08.004
TI - The anions and dianions of group 14 metalloles
T2 - Coordination Chemistry Reviews
AU - Saito, Masaichi
AU - Yoshioka, Michikazu
PY - 2005
DA - 2005/04/01
PB - Elsevier
SP - 765-780
IS - 7-8
VL - 249
SN - 0010-8545
SN - 1873-3840
ER -
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@article{2005_Saito,
author = {Masaichi Saito and Michikazu Yoshioka},
title = {The anions and dianions of group 14 metalloles},
journal = {Coordination Chemistry Reviews},
year = {2005},
volume = {249},
publisher = {Elsevier},
month = {apr},
url = {https://doi.org/10.1016/j.ccr.2004.08.004},
number = {7-8},
pages = {765--780},
doi = {10.1016/j.ccr.2004.08.004}
}
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MLA
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Saito, Masaichi, et al. “The anions and dianions of group 14 metalloles.” Coordination Chemistry Reviews, vol. 249, no. 7-8, Apr. 2005, pp. 765-780. https://doi.org/10.1016/j.ccr.2004.08.004.