Coordination Chemistry Reviews, volume 255, issue 13-14, pages 1460-1479
Recent advances in CO2/epoxide copolymerization—New strategies and cooperative mechanisms
Publication type: Journal Article
Publication date: 2011-07-01
Journal:
Coordination Chemistry Reviews
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 20.6
ISSN: 00108545
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The catalytic copolymerization of CO 2 with epoxides has been known for over 40 years. Even though many heterogeneous and homogeneous catalyst systems have been developed, catalyst activity and selectivity still remain too low for large scale industrial application. Recent investigations have identified new copolymerization pathways with strong evidence for cooperative (bifunctional) mechanisms. At high dilutions, traditional discrete mononuclear single-site catalyst systems generally show a loss in activity. This effect can be overcome with the help of recently developed dinuclear and binary linked systems that involve cooperative mechanisms and thus permit high catalyst efficiency. This review gives an overview on the most recent advances in CO 2 /epoxide copolymerization, new mechanistic studies and strategies for future catalyst developments.
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- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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STEPHAN K. et al. Recent advances in CO2/epoxide copolymerization—New strategies and cooperative mechanisms // Coordination Chemistry Reviews. 2011. Vol. 255. No. 13-14. pp. 1460-1479.
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STEPHAN K., Lehenmeier M. W., Anderson C. E., Rieger B. Recent advances in CO2/epoxide copolymerization—New strategies and cooperative mechanisms // Coordination Chemistry Reviews. 2011. Vol. 255. No. 13-14. pp. 1460-1479.
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TY - JOUR
DO - 10.1016/j.ccr.2010.12.002
UR - https://doi.org/10.1016/j.ccr.2010.12.002
TI - Recent advances in CO2/epoxide copolymerization—New strategies and cooperative mechanisms
T2 - Coordination Chemistry Reviews
AU - STEPHAN, KLAUS
AU - Lehenmeier, Maximilian W
AU - Anderson, Carly E
AU - Rieger, Bernhard
PY - 2011
DA - 2011/07/01 00:00:00
PB - Elsevier
SP - 1460-1479
IS - 13-14
VL - 255
SN - 0010-8545
ER -
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@article{2011_STEPHAN,
author = {KLAUS STEPHAN and Maximilian W Lehenmeier and Carly E Anderson and Bernhard Rieger},
title = {Recent advances in CO2/epoxide copolymerization—New strategies and cooperative mechanisms},
journal = {Coordination Chemistry Reviews},
year = {2011},
volume = {255},
publisher = {Elsevier},
month = {jul},
url = {https://doi.org/10.1016/j.ccr.2010.12.002},
number = {13-14},
pages = {1460--1479},
doi = {10.1016/j.ccr.2010.12.002}
}
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STEPHAN, KLAUS, et al. “Recent advances in CO2/epoxide copolymerization—New strategies and cooperative mechanisms.” Coordination Chemistry Reviews, vol. 255, no. 13-14, Jul. 2011, pp. 1460-1479. https://doi.org/10.1016/j.ccr.2010.12.002.