Coordination Chemistry Reviews, volume 295, pages 125-138
Structural diversity and photoluminescence of copper(I) carboxylates: From discrete complexes to infinite metal-based wires and helices
1
Department of Chemistry University at Albany, State University of New York 1400 Washington Avenue Albany NY 12222 USA
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Publication type: Journal Article
Publication date: 2015-07-01
Journal:
Coordination Chemistry Reviews
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 20.6
ISSN: 00108545
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Copper(I) carboxylates have rich photoluminescent properties and broad applications in catalysis, microelectronics, and bioinorganic chemistry. They also exhibit a remarkable structural diversity ranging from discrete complexes to infinite networks based on mono-, di-, tetra-, or hexanuclear copper(I) cores, including unique double-helical arrangements. These structural variations should have important implications on physical and chemical behavior of the resulting crystalline solids, but no structural analysis or structure–property correlations have been established for this family. This work provides the first overview of the types of structures exhibited by crystallographically characterized copper(I) carboxylates having no exogenous ligands, opening pathways for a better understanding of their properties and further advancement of their practical applications.
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Hietsoi O. et al. Structural diversity and photoluminescence of copper(I) carboxylates: From discrete complexes to infinite metal-based wires and helices // Coordination Chemistry Reviews. 2015. Vol. 295. pp. 125-138.
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Hietsoi O., Filatov A. Y., Dubceac C., Petrukhina M. A. Structural diversity and photoluminescence of copper(I) carboxylates: From discrete complexes to infinite metal-based wires and helices // Coordination Chemistry Reviews. 2015. Vol. 295. pp. 125-138.
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TY - JOUR
DO - 10.1016/j.ccr.2015.03.009
UR - https://doi.org/10.1016/j.ccr.2015.03.009
TI - Structural diversity and photoluminescence of copper(I) carboxylates: From discrete complexes to infinite metal-based wires and helices
T2 - Coordination Chemistry Reviews
AU - Hietsoi, Oleksandr
AU - Filatov, Alexander Yu.
AU - Dubceac, Cristina
AU - Petrukhina, M. A.
PY - 2015
DA - 2015/07/01 00:00:00
PB - Elsevier
SP - 125-138
VL - 295
SN - 0010-8545
ER -
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@article{2015_Hietsoi,
author = {Oleksandr Hietsoi and Alexander Yu. Filatov and Cristina Dubceac and M. A. Petrukhina},
title = {Structural diversity and photoluminescence of copper(I) carboxylates: From discrete complexes to infinite metal-based wires and helices},
journal = {Coordination Chemistry Reviews},
year = {2015},
volume = {295},
publisher = {Elsevier},
month = {jul},
url = {https://doi.org/10.1016/j.ccr.2015.03.009},
pages = {125--138},
doi = {10.1016/j.ccr.2015.03.009}
}