Coordination Chemistry Reviews, volume 331, pages 1-36
Ruthenium and osmium complexes in CC bond-forming reactions by borrowing hydrogen catalysis
Publication type: Journal Article
Publication date: 2017-01-01
Journal:
Coordination Chemistry Reviews
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 20.6
ISSN: 00108545
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
This review deals with the application of ruthenium and osmium complexes in C C bond-forming reactions by borrowing hydrogen (BH) or hydrogen autotransfer (HA) catalysis, describing the considerable progress made over the years by these metal-complexes in the α-alkylation of ketones, β-alkylation of secondary alcohols, C-alkylation of relatively inactivated substrates bearing fewer acidic α-hydrogens (acetonitriles, acetamides, esters, etc.) with alcohols, and in the formation of other C C bonds using alcohols as substrates (or reactants). The results obtained in a process based on ruthenium- and osmium-catalysed alcohol-unsaturate transfer hydrogenative C C couplings are also included. Moreover, mechanistic aspects related to these reactions are discussed.
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Citations by publishers
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1 publication, 0.61%
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Bentham Science
1 publication, 0.61%
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Thieme
1 publication, 0.61%
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Chelucci G. Ruthenium and osmium complexes in CC bond-forming reactions by borrowing hydrogen catalysis // Coordination Chemistry Reviews. 2017. Vol. 331. pp. 1-36.
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Chelucci G. Ruthenium and osmium complexes in CC bond-forming reactions by borrowing hydrogen catalysis // Coordination Chemistry Reviews. 2017. Vol. 331. pp. 1-36.
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TY - JOUR
DO - 10.1016/j.ccr.2016.10.002
UR - https://doi.org/10.1016/j.ccr.2016.10.002
TI - Ruthenium and osmium complexes in CC bond-forming reactions by borrowing hydrogen catalysis
T2 - Coordination Chemistry Reviews
AU - Chelucci, Giorgio
PY - 2017
DA - 2017/01/01 00:00:00
PB - Elsevier
SP - 1-36
VL - 331
SN - 0010-8545
ER -
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@article{2017_Chelucci,
author = {Giorgio Chelucci},
title = {Ruthenium and osmium complexes in CC bond-forming reactions by borrowing hydrogen catalysis},
journal = {Coordination Chemistry Reviews},
year = {2017},
volume = {331},
publisher = {Elsevier},
month = {jan},
url = {https://doi.org/10.1016/j.ccr.2016.10.002},
pages = {1--36},
doi = {10.1016/j.ccr.2016.10.002}
}