Coordination Chemistry Reviews, volume 404, pages 213098

A structural and spectroscopic overview of molecular lanthanide complexes with fluorinated O-donor ligands

Publication typeJournal Article
Publication date2020-02-01
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor20.6
ISSN00108545
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The lanthanide elements are prevalent in modern electronics, contrast agents, and phosphors. Precursors for luminescent materials frequently use fluorinated ligands to promote volatility for chemical vapor deposition methods. In molecular complexes, fluorination is also a commonly used technique to reduce energy loss during luminescence, and the oxophilicity of the lanthanide ions makes fluorinated alkoxides an attractive tool for the design of luminescent lanthanide complexes. Herein, the structural and photophysical properties of lanthanide complexes ligated by fluorinated alkoxides have been reviewed. Selected examples of several categories are presented in detail, including carboxylates, chelating and non-chelating ligands, and systems with up to three metal centers. Potential areas for further investigation are highlighted.

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Hyre A. S., Doerrer L. H. A structural and spectroscopic overview of molecular lanthanide complexes with fluorinated O-donor ligands // Coordination Chemistry Reviews. 2020. Vol. 404. p. 213098.
GOST all authors (up to 50) Copy
Hyre A. S., Doerrer L. H. A structural and spectroscopic overview of molecular lanthanide complexes with fluorinated O-donor ligands // Coordination Chemistry Reviews. 2020. Vol. 404. p. 213098.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1016/j.ccr.2019.213098
UR - https://doi.org/10.1016/j.ccr.2019.213098
TI - A structural and spectroscopic overview of molecular lanthanide complexes with fluorinated O-donor ligands
T2 - Coordination Chemistry Reviews
AU - Hyre, Ariel S
AU - Doerrer, Linda H.
PY - 2020
DA - 2020/02/01 00:00:00
PB - Elsevier
SP - 213098
VL - 404
SN - 0010-8545
ER -
BibTex
Cite this
BibTex Copy
@article{2020_Hyre,
author = {Ariel S Hyre and Linda H. Doerrer},
title = {A structural and spectroscopic overview of molecular lanthanide complexes with fluorinated O-donor ligands},
journal = {Coordination Chemistry Reviews},
year = {2020},
volume = {404},
publisher = {Elsevier},
month = {feb},
url = {https://doi.org/10.1016/j.ccr.2019.213098},
pages = {213098},
doi = {10.1016/j.ccr.2019.213098}
}
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