Coordination Chemistry Reviews, volume 476, pages 214876
Decoration and utilization of a special class of metal–organic frameworks containing the fluorine moiety
2
Institute of Physical Chemistry of the Polish Academy of Sciences, Kasprzaka 44/52 01-224, Warsaw, Poland
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Publication type: Journal Article
Publication date: 2023-02-01
Journal:
Coordination Chemistry Reviews
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 20.6
ISSN: 00108545
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
• Fluorinated metal organic frameworks (FMOFs) are one of the best candidate in MOFs. • FMOFs show great stability in water and under moist conditions due of their hydrophobic nature. • High electronegativity of the fluorine moiety makes it good candidate to interact with different hosts. • FMOFs have mostly been used for gas-adsorption/separation, separation of hydrocarbons, oil-spill removal, sensing and catalysis applications. • It has high thermal stability, rigid and highly porous structures, chemical stability, and hydrophobic nature. Fluorinated organic molecules are generally chemically stable and have low electric polarizability because of the high electronegativity of fluorine. The use of fluorinated organic and inorganic molecules to synthesize innumerable coordination compounds, such as metal–organic frameworks (MOFs), has had a significant effect on the field of material chemistry. The high electronegativity of the fluorine atom attached to the organic ligand/linker generates electropositive character on the other part of the linker. This electropositive character of the ligand means that it can easily interact with electron-rich guest molecules in different host–guest applications. The metal complex formed with these fluorinated moieties generates an electron-dense pore environment owing to the existence of fluorine atoms inside the voids. These properties make fluorinated MOFs (FMOFs) potential candidates to provide a range of properties, such as particular chemical adsorption sites and host-material flexibility. FMOFs are generally hydrophobic because of the existence of fluorine atoms inside the pores, which aids in removal of oil spills on water and adsorption/separation of different gases and hydrocarbons. The high chemical and aqueous stability of FMOFs make them excellent candidates for many applications under various conditions. The fluorine-lined channels of FMOFs show excellent affinity for gas molecules, and they can thus be used for gas storage/separation. Owing to these unusual properties, FMOFs have been widely used as gas-separation materials and for removal of hazardous impurities from aqueous systems. Herein, we review synthesis of FMOFs using different strategies, the characteristics of FMOFs, and the applications of FMOFs in various fields, including gas adsorption/separation, hydrocarbon adsorption/separation, dye adsorption, catalysis, and sensing of small molecules.
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Kumar S. et al. Decoration and utilization of a special class of metal–organic frameworks containing the fluorine moiety // Coordination Chemistry Reviews. 2023. Vol. 476. p. 214876.
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Kumar S., Mohan B., Fu C., Gupta V., Ren P. Decoration and utilization of a special class of metal–organic frameworks containing the fluorine moiety // Coordination Chemistry Reviews. 2023. Vol. 476. p. 214876.
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TY - JOUR
DO - 10.1016/j.ccr.2022.214876
UR - https://doi.org/10.1016/j.ccr.2022.214876
TI - Decoration and utilization of a special class of metal–organic frameworks containing the fluorine moiety
T2 - Coordination Chemistry Reviews
AU - Kumar, Sandeep
AU - Mohan, Brij
AU - Fu, Chuya
AU - Gupta, Vijay
AU - Ren, Peng
PY - 2023
DA - 2023/02/01 00:00:00
PB - Elsevier
SP - 214876
VL - 476
SN - 0010-8545
ER -
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@article{2023_Kumar,
author = {Sandeep Kumar and Brij Mohan and Chuya Fu and Vijay Gupta and Peng Ren},
title = {Decoration and utilization of a special class of metal–organic frameworks containing the fluorine moiety},
journal = {Coordination Chemistry Reviews},
year = {2023},
volume = {476},
publisher = {Elsevier},
month = {feb},
url = {https://doi.org/10.1016/j.ccr.2022.214876},
pages = {214876},
doi = {10.1016/j.ccr.2022.214876}
}