Chemical Engineering Journal, volume 392, pages 123650

Facile interfacial adhesion enabled LATP-based solid-state lithium metal battery

Zelin Yang 1
Hongyan Yuan 1
Chuanjian Zhou
Chuanjian Zhou 2
Yongmin Wu 3
Weiping Tang
Weiping Tang 3
Shangbin Sang
S. Sang 1, 2
Publication typeJournal Article
Publication date2020-07-01
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor15.1
ISSN13858947, 03009467
General Chemistry
General Chemical Engineering
Industrial and Manufacturing Engineering
Environmental Chemistry
Abstract
As a low-cost fast lithium ionic conductor with high shear modulus and ionic conductivity, Li1.3Al0.3Ti1.7(PO4)3 (LATP) is supposed to be one of the most promising ceramic electrolytes for high-energy solid-state batteries. However, the chemical reaction with lithium metal and the high interfacial impedance with solid electrodes make the ceramic electrolyte difficult to straightly apply to lithium metal batteries. Herein, a facile interfacial adhesion strategy is proposed to solve the addressed issues. The sticky polyethylene oxide (PEO) thin layer is served as interfacial adhesive to link the compact LATP ceramic electrolyte and the solid electrodes in consideration of its acceptable Li+ conducting capability and perfect compatibility with the tailored materials. Meantime, the PEO adhesive instead of PVDF binder is employed to glue the cathode components, enhancing the affinity to the PEO interlayer. As a result, the solid/solid interfacial resistance is decreased by two orders of magnitude. The solid-state Li/LATP/LiFePO4(LFP) cell with PEO adhesion is successfully activated, and exhibits steady cycling performance with high reversible capacity at the current no more than 0.5 C. As proposed interfacial adhesion strategy is simple but efficient to enable solid-state lithium metal batteries.

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Yang Z. et al. Facile interfacial adhesion enabled LATP-based solid-state lithium metal battery // Chemical Engineering Journal. 2020. Vol. 392. p. 123650.
GOST all authors (up to 50) Copy
Yang Z., Yuan H., Zhou C., Zhou C., Wu Y., Tang W., Tang W., Sang S., Sang S. Facile interfacial adhesion enabled LATP-based solid-state lithium metal battery // Chemical Engineering Journal. 2020. Vol. 392. p. 123650.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1016/j.cej.2019.123650
UR - https://doi.org/10.1016/j.cej.2019.123650
TI - Facile interfacial adhesion enabled LATP-based solid-state lithium metal battery
T2 - Chemical Engineering Journal
AU - Yang, Zelin
AU - Yuan, Hongyan
AU - Zhou, Chuanjian
AU - Wu, Yongmin
AU - Tang, Weiping
AU - Sang, Shangbin
AU - Sang, S.
AU - Zhou, Chuanjian
AU - Tang, Weiping
PY - 2020
DA - 2020/07/01 00:00:00
PB - Elsevier
SP - 123650
VL - 392
SN - 1385-8947
SN - 0300-9467
ER -
BibTex
Cite this
BibTex Copy
@article{2020_Yang,
author = {Zelin Yang and Hongyan Yuan and Chuanjian Zhou and Yongmin Wu and Weiping Tang and Shangbin Sang and S. Sang and Chuanjian Zhou and Weiping Tang},
title = {Facile interfacial adhesion enabled LATP-based solid-state lithium metal battery},
journal = {Chemical Engineering Journal},
year = {2020},
volume = {392},
publisher = {Elsevier},
month = {jul},
url = {https://doi.org/10.1016/j.cej.2019.123650},
pages = {123650},
doi = {10.1016/j.cej.2019.123650}
}
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