Chemical Engineering Journal, volume 425, pages 130535
Insight on air-induced degradation mechanism of Li7P3S11 to design a chemical-stable solid electrolyte with high Li2S utilization in all-solid-state Li/S batteries
Muhammad Khurram Tufail
,
Niaz Ahmad
,
Lei Zhou
,
Muhammad Faheem
,
Le Yang
,
Renjie Chen
1
,
Wen Yang
Publication type: Journal Article
Publication date: 2021-12-01
Journal:
Chemical Engineering Journal
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 15.1
ISSN: 13858947, 03009467
General Chemistry
General Chemical Engineering
Industrial and Manufacturing Engineering
Environmental Chemistry
Abstract
• A mechanistically driven approach to chemical stability of Li 7 P 3 S 11 solid electrolyte. • LZPSOI exhibited high ionic conductivity 3.01 mS cm −1 and improved air-stability. • The structure–property correlation is scrutinized by ex-situ approaches. • The high utilization of Li 2 S active material has been achieved. • The LZPSOI-based ASSLSBs unveiled higher initial capacity and coulombic efficiency. The ideal solid-state electrolyte must have exceptional chemical and electrochemical stability, high ionic conductivity, lower interfacial resistance and high active material utilization. Inspired by discovering new lithium thiophosphate superionic conductors for all-solid-state Li/S batteries (ASSLSBs), we designed and explored the local structure of Li 6.95 Zr 0.05 P 2.9 S 10.8 O 0.1 I 0.4 (LZPSOI) solid-state electrolyte, which owns a high ionic conductivity of 3.01 mS cm −1 with improved air-stability at RT. The structure–property correlation behavior of the chemical stability of LZPSOI electrolyte was sequentially premeditated by a combination of ex-situ XRD, MAS-NMR, XPS and SEM. A mechanistically driven approach has been extensively evaluated that the chemical stability of Li 7 P 3 S 11 could be enhanced via oxide doping, in which S 2- was partly replaced by O 2– in conductive structural units to yield POS 3 3- and P 2 OS 6 4- which was confirmed by XPS and 31 P MAS-NMR. The ASSLSBs assembled with LZPSOI electrolyte exhibited a remarkable initial discharge capacity of 932 mAh g −1 and a coulombic efficiency of 99.2% under 0.064 mA cm −2 at RT, compared to Li 7 P 3 S 11 counterpart. The exceptional cyclic performance was benefitted from higher electronic and ionic conductivities with LiI additive and additional reaction sites, which collectively enhanced the utilization of Li 2 S active material. This exploration gives birth to a potential contender as a solid-state electrolyte with high ionic conductivity and chemical stability to apply for next-generation ASSLSBs.
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1 publication, 1.96%
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- We do not take into account publications without a DOI.
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- Statistics recalculated weekly.
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Tufail M. K. et al. Insight on air-induced degradation mechanism of Li7P3S11 to design a chemical-stable solid electrolyte with high Li2S utilization in all-solid-state Li/S batteries // Chemical Engineering Journal. 2021. Vol. 425. p. 130535.
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Tufail M. K., Ahmad N., Zhou L., Faheem M., Yang L., Chen R., Yang W. Insight on air-induced degradation mechanism of Li7P3S11 to design a chemical-stable solid electrolyte with high Li2S utilization in all-solid-state Li/S batteries // Chemical Engineering Journal. 2021. Vol. 425. p. 130535.
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TY - JOUR
DO - 10.1016/j.cej.2021.130535
UR - https://doi.org/10.1016/j.cej.2021.130535
TI - Insight on air-induced degradation mechanism of Li7P3S11 to design a chemical-stable solid electrolyte with high Li2S utilization in all-solid-state Li/S batteries
T2 - Chemical Engineering Journal
AU - Tufail, Muhammad Khurram
AU - Ahmad, Niaz
AU - Zhou, Lei
AU - Faheem, Muhammad
AU - Yang, Le
AU - Chen, Renjie
AU - Yang, Wen
PY - 2021
DA - 2021/12/01 00:00:00
PB - Elsevier
SP - 130535
VL - 425
SN - 1385-8947
SN - 0300-9467
ER -
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@article{2021_Tufail,
author = {Muhammad Khurram Tufail and Niaz Ahmad and Lei Zhou and Muhammad Faheem and Le Yang and Renjie Chen and Wen Yang},
title = {Insight on air-induced degradation mechanism of Li7P3S11 to design a chemical-stable solid electrolyte with high Li2S utilization in all-solid-state Li/S batteries},
journal = {Chemical Engineering Journal},
year = {2021},
volume = {425},
publisher = {Elsevier},
month = {dec},
url = {https://doi.org/10.1016/j.cej.2021.130535},
pages = {130535},
doi = {10.1016/j.cej.2021.130535}
}