Chemical Engineering Journal, volume 429, pages 132399
LiN5: A novel pentazolate salt with high nitrogen content
Yuan-Gang XU
1
,
Lujia Ding
1
,
Feng Yang
1
,
Dongxue Li
2
,
Pengcheng Wang
1
,
Qiuhan Lin
1
,
Ming-Jen Lu
1
2
China National Quality Supervision Testing Center for Industrial Explosive Materials, Nanjing 210094, China
|
Publication type: Journal Article
Publication date: 2022-02-01
Journal:
Chemical Engineering Journal
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 15.1
ISSN: 13858947, 03009467
General Chemistry
General Chemical Engineering
Industrial and Manufacturing Engineering
Environmental Chemistry
Abstract
• A high nitrogen content cyclo -pentazolate salt LiN 5 was simply synthesized. • Single-crystal structures of LiN 5 ·3H 2 O and anhydrous LiN 5 framework were confirmed. • LiN 5 shows excellent detonation performance ( D = 11362 m s −1 ; P = 40.9 GPa). • LiN 5 exhibits excellent thermal stability with an exothermic peak of 153 °C. • LiN 5 is a promising candidate as a green primary explosive. A high energy cyclo -pentazolate ( cyclo -N 5 − ) salt with 90.98 % nitrogen content, LiN 5 , was synthesized by a simple metathesis reaction of AgN 5 and LiCl in deionized water. It was characterized by 15 N nuclear magnetic resonance, infrared and Raman spectroscopy, elemental analysis, thermogravimetry-mass (TG-MS) spectrometry, and differential scanning calorimetry. Besides, its trihydrate (LiN 5 ·3H 2 O) and anhydrous zeolitic architecture (LPF, lithium-pentazolate framework) structures were confirmed by single-crystal X-ray diffraction. LiN 5 achieved stability in air and under ambient conditions. It starts to decompose when heated to 133 °C (onset) under Ar 2 flow. Its relatively high density (1.75 g cm −3 ), impact and friction sensitivity (IS = 3 J; FS = 20 N), and calculated high heat of formation (3.44 kJ g −1 ), combined with its theorical superior detonation velocity and pressure ( D = 11362 m s −1 , P = 40.9 GPa), endow LiN 5 with potential as an environmentally primary explosive.
Top-30
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Citations by publishers
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9 publications, 26.47%
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1 publication, 2.94%
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1 publication, 2.94%
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Pleiades Publishing
1 publication, 2.94%
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Springer Nature
1 publication, 2.94%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 2.94%
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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XU Y. et al. LiN5: A novel pentazolate salt with high nitrogen content // Chemical Engineering Journal. 2022. Vol. 429. p. 132399.
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XU Y., Ding L., Yang F., Li D., Wang P., Lin Q., Lu M. LiN5: A novel pentazolate salt with high nitrogen content // Chemical Engineering Journal. 2022. Vol. 429. p. 132399.
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TY - JOUR
DO - 10.1016/j.cej.2021.132399
UR - https://doi.org/10.1016/j.cej.2021.132399
TI - LiN5: A novel pentazolate salt with high nitrogen content
T2 - Chemical Engineering Journal
AU - XU, Yuan-Gang
AU - Ding, Lujia
AU - Yang, Feng
AU - Li, Dongxue
AU - Wang, Pengcheng
AU - Lin, Qiuhan
AU - Lu, Ming-Jen
PY - 2022
DA - 2022/02/01 00:00:00
PB - Elsevier
SP - 132399
VL - 429
SN - 1385-8947
SN - 0300-9467
ER -
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@article{2022_XU,
author = {Yuan-Gang XU and Lujia Ding and Feng Yang and Dongxue Li and Pengcheng Wang and Qiuhan Lin and Ming-Jen Lu},
title = {LiN5: A novel pentazolate salt with high nitrogen content},
journal = {Chemical Engineering Journal},
year = {2022},
volume = {429},
publisher = {Elsevier},
month = {feb},
url = {https://doi.org/10.1016/j.cej.2021.132399},
pages = {132399},
doi = {10.1016/j.cej.2021.132399}
}
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