Chemical Engineering Journal, volume 430, pages 132991
Thin, flexible sulfide-based electrolyte film and its interface engineering for high performance solid-state lithium metal batteries
Hong Liu
1
,
Pingge He
,
Boyun Huang
2
,
Guoxu Wang
1
,
Yuhao Liang
,
Yu-Hao Liang
1
,
Chao Wang
1
,
Li‐Zhen Fan
1
2
Department of Chemistry and Biochemistry, University of California, 1156, High Street, Santa Cruz, CA, 95064, USA
|
Publication type: Journal Article
Publication date: 2022-02-01
Journal:
Chemical Engineering Journal
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 15.1
ISSN: 13858947, 03009467
General Chemistry
General Chemical Engineering
Industrial and Manufacturing Engineering
Environmental Chemistry
Abstract
• An ultrathin (∼60 μm) and flexible sulfide-based electrolyte film is prepared. • The interfacial compatibility is tremendously enhanced through a buffer layer prepared by in-situ polymerization. • Solid-state lithium metal batteries show high safety and superior cycling performance. Sulfide electrolytes have attracted increasing attention due to their ultrahigh ionic conductivity and intrinsically soft properties. However, current solid-state lithium metal batteries (SSLMBs) based on sulfide electrolyte generally suffer from poor electrochemical performance due to the thick electrolyte layer and its terrible compatibility with Li metal anode. Herein, an ultrathin (∼60 μm) sulfide-based electrolyte film is prepared by a scalable slurry-casting method using Li 10 GeP 2 S 12 , polyethylene oxide, (3-chloropropyl)trimethoxysilane and nylon mesh (as a scaffold). Such film exhibits high ambient-temperature ionic conductivity (2.4 × 10 −4 S cm −1 ), wide electrochemical window (4.7 V versus Li/Li + ), outstanding heat-resistance and high mechanical strength (13.8 MPa). Furthermore, the compatibility of anode interface has been tremendously enhanced by the interface engineering of fluorine-rich gel protective layer on Li anode (Gel-Li) via in-situ polymerization, which can effectively prevent the lithium dendrite growth and endow outstanding long-term cyclic stability of the Li symmetric battery. As a result, the assembled MWCNT@S/Gel-Li and LiNbO 3 @LiNi 0.6 Mn 0.2 Co 0.2 O 2 /Gel-Li batteries based on such electrolyte film display desirable discharge specific capacities and outstanding cycling stability at ambient-temperature. In addition, the integrated pouch cell can operate well even under harsh environments of bending, cutting, punching situations, demonstrating that such thin electrolyte and its interface engineering applied in SSLMBs with high safety and durability.
Top-30
Citations by journals
|
1
2
3
4
5
6
|
|
|
Energy Storage Materials
6 publications, 11.11%
|
|
|
Chemical Engineering Journal
5 publications, 9.26%
|
|
|
Advanced Energy Materials
4 publications, 7.41%
|
|
|
Journal of Power Sources
4 publications, 7.41%
|
|
|
Nano-Micro Letters
2 publications, 3.7%
|
|
|
Journal of Materiomics
2 publications, 3.7%
|
|
|
Advanced Materials
2 publications, 3.7%
|
|
|
eTransportation
2 publications, 3.7%
|
|
|
Journal of Energy Storage
2 publications, 3.7%
|
|
|
Nano Letters
1 publication, 1.85%
|
|
|
Battery Energy
1 publication, 1.85%
|
|
|
Journal of Advanced Ceramics
1 publication, 1.85%
|
|
|
Electrochimica Acta
1 publication, 1.85%
|
|
|
Journal of Colloid and Interface Science
1 publication, 1.85%
|
|
|
Journal of Electroanalytical Chemistry
1 publication, 1.85%
|
|
|
Acta Materialia
1 publication, 1.85%
|
|
|
Nano Research
1 publication, 1.85%
|
|
|
ACS Applied Polymer Materials
1 publication, 1.85%
|
|
|
InfoMat
1 publication, 1.85%
|
|
|
Advanced Functional Materials
1 publication, 1.85%
|
|
|
Interdisciplinary Materials
1 publication, 1.85%
|
|
|
Advanced Materials Interfaces
1 publication, 1.85%
|
|
|
ACS applied materials & interfaces
1 publication, 1.85%
|
|
|
Materials Futures
1 publication, 1.85%
|
|
|
Materials Chemistry Frontiers
1 publication, 1.85%
|
|
|
Energy Storage
1 publication, 1.85%
|
|
|
ACS Nano
1 publication, 1.85%
|
|
|
Angewandte Chemie
1 publication, 1.85%
|
|
|
Angewandte Chemie - International Edition
1 publication, 1.85%
|
|
|
Small
1 publication, 1.85%
|
|
|
1
2
3
4
5
6
|
Citations by publishers
|
5
10
15
20
25
|
|
|
Elsevier
25 publications, 46.3%
|
|
|
Wiley
15 publications, 27.78%
|
|
|
American Chemical Society (ACS)
4 publications, 7.41%
|
|
|
Springer Nature
3 publications, 5.56%
|
|
|
Chinese Ceramic Society
2 publications, 3.7%
|
|
|
Tsinghua University Press
1 publication, 1.85%
|
|
|
IOP Publishing
1 publication, 1.85%
|
|
|
Royal Society of Chemistry (RSC)
1 publication, 1.85%
|
|
|
The Electrochemical Society
1 publication, 1.85%
|
|
|
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 1.85%
|
|
|
5
10
15
20
25
|
- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2022,2023,2024],"ids":[0,0,0],"codes":[0,0,0],"imageUrls":["","",""],"datasets":[{"label":"Citations number","data":[13,26,15],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6"],"percentage":["24.07","48.15","27.78"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["Energy Storage Materials","Chemical Engineering Journal","Advanced Energy Materials","Journal of Power Sources","Nano-Micro Letters","Journal of Materiomics","Advanced Materials","eTransportation","Journal of Energy Storage","Nano Letters","Battery Energy","Journal of Advanced Ceramics","Electrochimica Acta","Journal of Colloid and Interface Science","Journal of Electroanalytical Chemistry","Acta Materialia","Nano Research","ACS Applied Polymer Materials","InfoMat","Advanced Functional Materials","Interdisciplinary Materials","Advanced Materials Interfaces","ACS applied materials & interfaces","Materials Futures","Materials Chemistry Frontiers","Energy Storage","ACS Nano","Angewandte Chemie","Angewandte Chemie - International Edition","Small"],"ids":[3858,16275,22475,14844,7765,9151,25159,25487,18623,10312,29981,5243,15613,24202,22454,6469,12211,25373,25964,7715,30049,18764,1458,30861,7063,28244,8724,25450,19215,9872],"codes":[0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/ZBf59wI1SMgSL89rU8cJXRfzrfAz8slfIClYmcuk_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/LsKy6OnmmmRGcAU6CZgWQvNiP1polbaSLNrN7zqj_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp"],"datasets":[{"label":"","data":[6,5,4,4,2,2,2,2,2,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[11.11,9.26,7.41,7.41,3.7,3.7,3.7,3.7,3.7,1.85,1.85,1.85,1.85,1.85,1.85,1.85,1.85,1.85,1.85,1.85,1.85,1.85,1.85,1.85,1.85,1.85,1.85,1.85,1.85,1.85],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["Elsevier","Wiley","American Chemical Society (ACS)","Springer Nature","Chinese Ceramic Society","Tsinghua University Press","IOP Publishing","Royal Society of Chemistry (RSC)","The Electrochemical Society","Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii"],"ids":[17,11,40,8,2953,1836,2075,123,6916,9422],"codes":[0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","","\/storage\/images\/resized\/ZBf59wI1SMgSL89rU8cJXRfzrfAz8slfIClYmcuk_medium.webp","\/storage\/images\/resized\/LsKy6OnmmmRGcAU6CZgWQvNiP1polbaSLNrN7zqj_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/s6nfxitVCZUsdJiJZESaAXqdmMJxom8q4Ps6ayL2_medium.webp","\/storage\/images\/resized\/9Mus3KG1Tkd7Bwaurt8H3RwWh0CxRlGoO6ng9UK1_medium.webp"],"datasets":[{"label":"","data":[25,15,4,3,2,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[46.3,27.78,7.41,5.56,3.7,1.85,1.85,1.85,1.85,1.85],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartiles":{"type":"bar","data":{"show":true,"labels":[2022,2023,2024],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0,0,0],"percentage":["0","0","0"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[0,1,1],"percentage":["0","1.85","1.85"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[0,0,0],"percentage":["0","0","0"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[12,23,14],"percentage":["22.22","42.59","25.93"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[1,2,0],"percentage":["1.85","3.7","0"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by SCImago per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartilesWs":{"type":"bar","data":{"show":true,"labels":[2022,2023,2024],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0,0,0],"percentage":["0","0","0"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[0,0,1],"percentage":["0","0","1.85"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[2,0,0],"percentage":["3.7","0","0"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[10,22,14],"percentage":["18.52","40.74","25.93"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[1,4,0],"percentage":["1.85","7.41","0"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by WoS per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
Cite this
GOST |
RIS |
BibTex
Cite this
GOST
Copy
Liu H. et al. Thin, flexible sulfide-based electrolyte film and its interface engineering for high performance solid-state lithium metal batteries // Chemical Engineering Journal. 2022. Vol. 430. p. 132991.
GOST all authors (up to 50)
Copy
Liu H., He P., Huang B., Wang G., Liang Y., Liang Y., Wang C., Wang C., Fan L. Thin, flexible sulfide-based electrolyte film and its interface engineering for high performance solid-state lithium metal batteries // Chemical Engineering Journal. 2022. Vol. 430. p. 132991.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/j.cej.2021.132991
UR - https://doi.org/10.1016/j.cej.2021.132991
TI - Thin, flexible sulfide-based electrolyte film and its interface engineering for high performance solid-state lithium metal batteries
T2 - Chemical Engineering Journal
AU - He, Pingge
AU - Wang, Guoxu
AU - Liang, Yuhao
AU - Wang, Chao
AU - Fan, Li‐Zhen
AU - Liu, Hong
AU - Huang, Boyun
AU - Liang, Yu-Hao
AU - Wang, Chao
PY - 2022
DA - 2022/02/01 00:00:00
PB - Elsevier
SP - 132991
VL - 430
SN - 1385-8947
SN - 0300-9467
ER -
Cite this
BibTex
Copy
@article{2022_Liu,
author = {Pingge He and Guoxu Wang and Yuhao Liang and Chao Wang and Li‐Zhen Fan and Hong Liu and Boyun Huang and Yu-Hao Liang and Chao Wang},
title = {Thin, flexible sulfide-based electrolyte film and its interface engineering for high performance solid-state lithium metal batteries},
journal = {Chemical Engineering Journal},
year = {2022},
volume = {430},
publisher = {Elsevier},
month = {feb},
url = {https://doi.org/10.1016/j.cej.2021.132991},
pages = {132991},
doi = {10.1016/j.cej.2021.132991}
}