Chemical Engineering Journal, volume 435, pages 135106

Porous poly(vinylidene fluoride) supported three-dimensional poly(ethylene glycol) thin solid polymer electrolyte for flexible high temperature all-solid-state lithium metal batteries

ZHIYAN WANG ^{1, 2}

Qingya Guo ²

Rongrong Jiang ²

Shungui Deng ²

Junfeng Ma ²

Ping Cui ^{1, 2}

Xiayin Yao ^{1, 2}

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Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, PR China |

Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, PR China |

Publication type: Journal Article

Publication date: 2022-05-01

Elsevier

Journal: Chemical Engineering Journal

Quartile SCImago

Quartile WOS

Impact factor: 15.1

ISSN: 13858947, 03009467

DOI: 10.1016/j.cej.2022.135106

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General Chemistry

General Chemical Engineering

Industrial and Manufacturing Engineering

Environmental Chemistry

Abstract

• The thin PVDF@PEG SPE (≈20 μm) was prepared by in-situ thermal curing. • The thin SPE possesses an ultrahigh ionic conductance of 75.7 mS at 30 °C. • The Li/PVDF@PEG/Li cell can be stable cycled more than 3200 h at 60 and 100 °C. • LiFePO 4 /PVDF@PEG/Li battery can stable for 1000 cycles under 1C at 60 and 100 °C. Solid polymer electrolytes (SPEs) are promising candidates for the next-generation all-solid-state batteries due to their good flexibility as well as safety. However, the low ionic conductivity, uncontrolled lithium dendrite growth, poor cyclic performance and high temperature intolerance are still great challenges for their widely applications. In this work, a flexible and dense poly(vinylidene fluoride)/poly(ethylene glycol) (PVDF@PEG) SPE is designed and fabricated via an in-situ thermocuring method, which exhibits a high ionic conductivity of 8.03 × 10 −5 S cm −1 at 30 °C and excellent electrochemical stability window of 5.2 V. More importantly, the Li/PVDF@PEG/Li symmetric cell can be continuously cycled at 0.1 mA cm −2 more than 3200 h without short-circuit at both 60 and 100 °C. Owing to these outstanding merits, the LiFePO 4 /PVDF@PEG/Li pouch cell delivered a high discharge specific capacity of 122.8 mAh g −1 after 1000 cycles at 1C with a capacity retention of 86.36% under 60 °C. Notably, the LiFePO 4 //Li pouch cell also shows excellent cycle stability at 100 °C, exhibiting reversible capacities from 155.5 to 123.1 mAh g −1 under 1C after 1000 cycles.

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Chemical Engineering Journal	Chemical Engineering Journal, 8, 8.79% Chemical Engineering Journal 8 publications, 8.79%
ACS Applied Energy Materials	ACS Applied Energy Materials, 7, 7.69% ACS Applied Energy Materials 7 publications, 7.69%
ACS applied materials & interfaces	ACS applied materials & interfaces, 5, 5.49% ACS applied materials & interfaces 5 publications, 5.49%
Journal of Materials Chemistry A	Journal of Materials Chemistry A, 5, 5.49% Journal of Materials Chemistry A 5 publications, 5.49%
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Journal of Membrane Science	Journal of Membrane Science, 3, 3.3% Journal of Membrane Science 3 publications, 3.3%
Journal of Power Sources	Journal of Power Sources, 3, 3.3% Journal of Power Sources 3 publications, 3.3%
Advanced Materials	Advanced Materials, 3, 3.3% Advanced Materials 3 publications, 3.3%
ACS Applied Polymer Materials	ACS Applied Polymer Materials, 2, 2.2% ACS Applied Polymer Materials 2 publications, 2.2%
Electrochimica Acta	Electrochimica Acta, 2, 2.2% Electrochimica Acta 2 publications, 2.2%
Journal of Energy Storage	Journal of Energy Storage, 2, 2.2% Journal of Energy Storage 2 publications, 2.2%
Advanced Energy Materials	Advanced Energy Materials, 2, 2.2% Advanced Energy Materials 2 publications, 2.2%
Industrial & Engineering Chemistry Research	Industrial & Engineering Chemistry Research, 2, 2.2% Industrial & Engineering Chemistry Research 2 publications, 2.2%
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ACS Sustainable Chemistry and Engineering	ACS Sustainable Chemistry and Engineering, 2, 2.2% ACS Sustainable Chemistry and Engineering 2 publications, 2.2%
Physical Chemistry Chemical Physics	Physical Chemistry Chemical Physics, 2, 2.2% Physical Chemistry Chemical Physics 2 publications, 2.2%
Nanoscale	Nanoscale, 2, 2.2% Nanoscale 2 publications, 2.2%
Materials Chemistry Frontiers	Materials Chemistry Frontiers, 2, 2.2% Materials Chemistry Frontiers 2 publications, 2.2%
Energy & Fuels	Energy & Fuels, 2, 2.2% Energy & Fuels 2 publications, 2.2%
Macromolecular Chemistry and Physics	Macromolecular Chemistry and Physics, 1, 1.1% Macromolecular Chemistry and Physics 1 publication, 1.1%
Advanced Functional Materials	Advanced Functional Materials, 1, 1.1% Advanced Functional Materials 1 publication, 1.1%
Carbon Energy	Carbon Energy, 1, 1.1% Carbon Energy 1 publication, 1.1%
Chemical Physics Letters	Chemical Physics Letters, 1, 1.1% Chemical Physics Letters 1 publication, 1.1%
Ionics	Ionics, 1, 1.1% Ionics 1 publication, 1.1%
Green Energy and Environment	Green Energy and Environment, 1, 1.1% Green Energy and Environment 1 publication, 1.1%
eTransportation	eTransportation, 1, 1.1% eTransportation 1 publication, 1.1%
Energy & Environmental Materials	Energy & Environmental Materials, 1, 1.1% Energy & Environmental Materials 1 publication, 1.1%
ChemPlusChem	ChemPlusChem, 1, 1.1% ChemPlusChem 1 publication, 1.1%
Journal of Solid State Electrochemistry	Journal of Solid State Electrochemistry, 1, 1.1% Journal of Solid State Electrochemistry 1 publication, 1.1%
	1 2 3 4 5 6 7 8

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	5 10 15 20 25 30
Elsevier	Elsevier, 28, 30.77% Elsevier 28 publications, 30.77%
American Chemical Society (ACS)	American Chemical Society (ACS), 22, 24.18% American Chemical Society (ACS) 22 publications, 24.18%
Wiley	Wiley, 16, 17.58% Wiley 16 publications, 17.58%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 16, 17.58% Royal Society of Chemistry (RSC) 16 publications, 17.58%
The Electrochemical Society	The Electrochemical Society, 4, 4.4% The Electrochemical Society 4 publications, 4.4%
Springer Nature	Springer Nature, 3, 3.3% Springer Nature 3 publications, 3.3%
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii	Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii, 1, 1.1% Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii 1 publication, 1.1%
Higher Education Press	Higher Education Press, 1, 1.1% Higher Education Press 1 publication, 1.1%
	5 10 15 20 25 30

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WANG Z. et al. Porous poly(vinylidene fluoride) supported three-dimensional poly(ethylene glycol) thin solid polymer electrolyte for flexible high temperature all-solid-state lithium metal batteries // Chemical Engineering Journal. 2022. Vol. 435. p. 135106.

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WANG Z., Guo Q., Jiang R., Deng S., Ma J., Cui P., Yao X. Porous poly(vinylidene fluoride) supported three-dimensional poly(ethylene glycol) thin solid polymer electrolyte for flexible high temperature all-solid-state lithium metal batteries // Chemical Engineering Journal. 2022. Vol. 435. p. 135106.

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RIS Copy

TY - JOUR

DO - 10.1016/j.cej.2022.135106

UR - https://doi.org/10.1016/j.cej.2022.135106

TI - Porous poly(vinylidene fluoride) supported three-dimensional poly(ethylene glycol) thin solid polymer electrolyte for flexible high temperature all-solid-state lithium metal batteries

T2 - Chemical Engineering Journal

AU - WANG, ZHIYAN

AU - Guo, Qingya

AU - Jiang, Rongrong

AU - Deng, Shungui

AU - Ma, Junfeng

AU - Cui, Ping

AU - Yao, Xiayin

PY - 2022

DA - 2022/05/01 00:00:00

PB - Elsevier

SP - 135106

VL - 435

SN - 1385-8947

SN - 0300-9467

ER -

BibTex

Cite this

BibTex Copy

@article{2022_WANG,

author = {ZHIYAN WANG and Qingya Guo and Rongrong Jiang and Shungui Deng and Junfeng Ma and Ping Cui and Xiayin Yao},

title = {Porous poly(vinylidene fluoride) supported three-dimensional poly(ethylene glycol) thin solid polymer electrolyte for flexible high temperature all-solid-state lithium metal batteries},

journal = {Chemical Engineering Journal},

year = {2022},

volume = {435},

publisher = {Elsevier},

month = {may},

url = {https://doi.org/10.1016/j.cej.2022.135106},

pages = {135106},

doi = {10.1016/j.cej.2022.135106}

}

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Publisher

Elsevier

Journal

Chemical Engineering Journal

Quartile SCImago

Quartile WOS

Impact factor

15.1

ISSN

13858947 (Print)
03009467 (Print)

Profiles

Yao, Xiayin Y