Chemical Engineering Journal, volume 449, pages 137682
Stabilizing solid electrolyte/Li interface via polymer-in-salt artificial protection layer for high-rate and stable lithium metal batteries
Long Pan
1
,
Shuo Sun
1
,
Genxi Yu
1
,
Xiongxiong Liu
1
,
Shengfa Feng
1
,
Wei Zhang
1
,
Muhammadali Turgunov
2
,
Yaping Wang
1
,
Publication type: Journal Article
Publication date: 2022-12-01
Journal:
Chemical Engineering Journal
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 15.1
ISSN: 13858947, 03009467
General Chemistry
General Chemical Engineering
Industrial and Manufacturing Engineering
Environmental Chemistry
Abstract
• A polymer-in-salt (PiS) interlayer is adopted to stabilize the solid electrolyte/Li interface. • PVDF-HFP with 60 wt% LiTFSI shows high conductivity, high stability towards Li metal and easy processing ability. • The LFP||LATP@PiS||Li full cell showed outstanding rate capability (124.0 mA·h·g −1 at 2.0C under 60 °C) and cyclability. Solid electrolytes are fundamental for next-generation solid-state Li-metal batteries that promise high energy density and safety. However, various solid electrolytes suffer from chemical/electrochemical instability against Li metal and poor interfacial contact with electrodes. Herein, a polymer-in-salt (PiS) artificial protection layer composed of fluoropolymer in highly-concentrated lithium salt (labeled as PiSPL) is introduced to address these problems using NASICON-type Li 1.3 Al 0.3 Ti 1.7 (PO 4 ) 3 (LATP) as a typical solid electrolyte. The resulted PiSPL layer exhibits small thickness (10 μm), good chemical/electrochemical stability, and excellent ionic conductivity (0.5 and 1.8 mS cm −1 at 25 and 60 °C, respectively). These properties endow the LATP/Li interface with improved contact, favorable Li + diffusion, and, most importantly, inhibited interfacial reactions, which is examined using ex-situ X-ray photoelectron spectroscopy and electrochemical analyses and morphological observations. Consequently, Li||LATP@PiSPL||Li symmetric cells can deliver small overpotentials at various current densities and long lifetime at 0.16 mA cm −2 over 400 h. On the contrary, the same configuration cells with LATP die after only 50 h. Moreover, the LiFePO 4 ||LATP@PiSPL||Li solid-state full cells exhibit excellent rate capability (124.0 mA h g −1 at 2.0C) and cyclability (148.9 and 140.6 mA h g −1 after 200 cycles at 0.2C and 300 cycles at 1.0C, respectively). The PiS strategy represents a general and effective approach to stabilize various solid electrolyte/Li interfaces to push solid-state Li-metal batteries forward.
Top-30
Citations by journals
|
1
2
|
|
|
Chemical Engineering Journal
2 publications, 8.7%
|
|
|
Journal of Energy Storage
2 publications, 8.7%
|
|
|
Energy Storage Materials
2 publications, 8.7%
|
|
|
Small
2 publications, 8.7%
|
|
|
Nanotechnology
1 publication, 4.35%
|
|
|
Batteries
1 publication, 4.35%
|
|
|
ACS Omega
1 publication, 4.35%
|
|
|
Polymer
1 publication, 4.35%
|
|
|
ACS Applied Energy Materials
1 publication, 4.35%
|
|
|
Chemical Science
1 publication, 4.35%
|
|
|
Surface and Coatings Technology
1 publication, 4.35%
|
|
|
Ionics
1 publication, 4.35%
|
|
|
Electrochimica Acta
1 publication, 4.35%
|
|
|
Journal of the Electrochemical Society
1 publication, 4.35%
|
|
|
Advanced Functional Materials
1 publication, 4.35%
|
|
|
Russian Chemical Reviews
1 publication, 4.35%
|
|
|
International Journal of Electrochemical Science
1 publication, 4.35%
|
|
|
EcoEnergy
1 publication, 4.35%
|
|
|
Chinese Chemical Letters
1 publication, 4.35%
|
|
|
1
2
|
Citations by publishers
|
2
4
6
8
10
12
|
|
|
Elsevier
11 publications, 47.83%
|
|
|
Wiley
4 publications, 17.39%
|
|
|
American Chemical Society (ACS)
2 publications, 8.7%
|
|
|
IOP Publishing
1 publication, 4.35%
|
|
|
Multidisciplinary Digital Publishing Institute (MDPI)
1 publication, 4.35%
|
|
|
Royal Society of Chemistry (RSC)
1 publication, 4.35%
|
|
|
Springer Nature
1 publication, 4.35%
|
|
|
The Electrochemical Society
1 publication, 4.35%
|
|
|
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 4.35%
|
|
|
2
4
6
8
10
12
|
- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2022,2023,2024],"ids":[0,0,0],"codes":[0,0,0],"imageUrls":["","",""],"datasets":[{"label":"Citations number","data":[1,5,17],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6"],"percentage":["4.35","21.74","73.91"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["Chemical Engineering Journal","Journal of Energy Storage","Energy Storage Materials","Small","Nanotechnology","Batteries","ACS Omega","Polymer","ACS Applied Energy Materials","Chemical Science","Surface and Coatings Technology","Ionics","Electrochimica Acta","Journal of the Electrochemical Society","Advanced Functional Materials","Russian Chemical Reviews","International Journal of Electrochemical Science","EcoEnergy","Chinese Chemical Letters"],"ids":[16275,18623,3858,9872,16187,19798,18901,19955,6419,9646,12521,12191,15613,5297,7715,23802,15403,55176,20341],"codes":[0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/LsKy6OnmmmRGcAU6CZgWQvNiP1polbaSLNrN7zqj_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/s6nfxitVCZUsdJiJZESaAXqdmMJxom8q4Ps6ayL2_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/9Mus3KG1Tkd7Bwaurt8H3RwWh0CxRlGoO6ng9UK1_medium.webp","","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp"],"datasets":[{"label":"","data":[2,2,2,2,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[8.7,8.7,8.7,8.7,4.35,4.35,4.35,4.35,4.35,4.35,4.35,4.35,4.35,4.35,4.35,4.35,4.35,4.35,4.35],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["Elsevier","Wiley","American Chemical Society (ACS)","IOP Publishing","Multidisciplinary Digital Publishing Institute (MDPI)","Royal Society of Chemistry (RSC)","Springer Nature","The Electrochemical Society","Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii"],"ids":[17,11,40,2075,202,123,8,6916,9422],"codes":[0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/LsKy6OnmmmRGcAU6CZgWQvNiP1polbaSLNrN7zqj_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/s6nfxitVCZUsdJiJZESaAXqdmMJxom8q4Ps6ayL2_medium.webp","\/storage\/images\/resized\/9Mus3KG1Tkd7Bwaurt8H3RwWh0CxRlGoO6ng9UK1_medium.webp"],"datasets":[{"label":"","data":[11,4,2,1,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[47.83,17.39,8.7,4.35,4.35,4.35,4.35,4.35,4.35],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartiles":{"type":"bar","data":{"show":true,"labels":[2022,2023,2024],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0,0,0],"percentage":["0","0","0"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[0,0,1],"percentage":["0","0","4.35"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[0,1,1],"percentage":["0","4.35","4.35"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[1,4,14],"percentage":["4.35","17.39","60.87"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[0,0,1],"percentage":["0","0","4.35"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by SCImago per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartilesWs":{"type":"bar","data":{"show":true,"labels":[2022,2023,2024],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0,0,1],"percentage":["0","0","4.35"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[0,0,0],"percentage":["0","0","0"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[1,3,2],"percentage":["4.35","13.04","8.7"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[0,2,13],"percentage":["0","8.7","56.52"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[0,0,1],"percentage":["0","0","4.35"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by WoS per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
Cite this
GOST |
RIS |
BibTex
Cite this
GOST
Copy
Pan L. et al. Stabilizing solid electrolyte/Li interface via polymer-in-salt artificial protection layer for high-rate and stable lithium metal batteries // Chemical Engineering Journal. 2022. Vol. 449. p. 137682.
GOST all authors (up to 50)
Copy
Pan L., Sun S., Yu G., Liu X., Feng S., Zhang W., Turgunov M., Wang Y., Sun Z. Stabilizing solid electrolyte/Li interface via polymer-in-salt artificial protection layer for high-rate and stable lithium metal batteries // Chemical Engineering Journal. 2022. Vol. 449. p. 137682.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/j.cej.2022.137682
UR - https://doi.org/10.1016/j.cej.2022.137682
TI - Stabilizing solid electrolyte/Li interface via polymer-in-salt artificial protection layer for high-rate and stable lithium metal batteries
T2 - Chemical Engineering Journal
AU - Pan, Long
AU - Sun, Shuo
AU - Yu, Genxi
AU - Liu, Xiongxiong
AU - Feng, Shengfa
AU - Zhang, Wei
AU - Turgunov, Muhammadali
AU - Wang, Yaping
AU - Sun, Zheng-Ming
PY - 2022
DA - 2022/12/01 00:00:00
PB - Elsevier
SP - 137682
VL - 449
SN - 1385-8947
SN - 0300-9467
ER -
Cite this
BibTex
Copy
@article{2022_Pan,
author = {Long Pan and Shuo Sun and Genxi Yu and Xiongxiong Liu and Shengfa Feng and Wei Zhang and Muhammadali Turgunov and Yaping Wang and Zheng-Ming Sun},
title = {Stabilizing solid electrolyte/Li interface via polymer-in-salt artificial protection layer for high-rate and stable lithium metal batteries},
journal = {Chemical Engineering Journal},
year = {2022},
volume = {449},
publisher = {Elsevier},
month = {dec},
url = {https://doi.org/10.1016/j.cej.2022.137682},
pages = {137682},
doi = {10.1016/j.cej.2022.137682}
}
Profiles