Ceramics International, volume 42, issue 4, pages 5546-5552

Effect of composition on lithium-ion conductivity for perovskite-type lithium–strontium–tantalum–zirconium-oxide solid electrolytes

KEISUKE KIMURA ¹

Kota Wagatsuma ¹

Tomohiro Tojo ¹

Ryoji Inada ¹

Yoji Sakurai ¹

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Department of Electrical and Electronic Information Engineering Toyohashi University of Technology 1-1 Hibarigaoka Tempaku-cho Toyohashi Aichi 441-8580 Japan |

Publication type: Journal Article

Publication date: 2016-03-01

Elsevier

Journal: Ceramics International

Quartile SCImago

Quartile WOS

Impact factor: 5.2

ISSN: 02728842

DOI: 10.1016/j.ceramint.2015.12.133

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Materials Chemistry

Surfaces, Coatings and Films

Ceramics and Composites

Electronic, Optical and Magnetic Materials

Process Chemistry and Technology

Abstract

We synthesized Li2x−ySr1−xTayZr1−yO3 (LSTZ, x=0.75y) with various Ta contents y=0.60, 0.70, 0.75, 0.77 and 0.8 via a conventional solid state reaction method and investigated their crystal phase, microstructure and lithium-ion conductivity. Almost single phase perovskite-type structured LSTZ was obtained at y=0.60–0.75 and their lattice sizes were increased with increasing y, indicating that Sr2+ and Zr4+ are successfully substituted by Li+ and Ta5+ with smaller ionic radii in these three samples. On the other hand, LSTZ with higher Ta contents y=0.77 and 0.8 included some impurity phases such as LiTaO3, SrTa2O6 and Sr2Ta2O7. A solid solution range for Ta into Zr site for LSTZ is expected to be y≤0.75. Both the bulk and total (bulk+grain-boundary) ionic conductivity of LSTZ monotonically increased with y from 0.60 to 0.75. Maximum bulk and total (bulk+grain-boundary) conductivities of 2.8×10−4 S cm−1 and 2.0×10−4 S cm−1 at 27 °C were obtained in LSTZ with y=0.75.

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Springer Nature	Springer Nature, 3, 7.5% Springer Nature 3 publications, 7.5%
Wiley	Wiley, 3, 7.5% Wiley 3 publications, 7.5%
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American Chemical Society (ACS)	American Chemical Society (ACS), 2, 5% American Chemical Society (ACS) 2 publications, 5%
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American Institute of Physics (AIP)	American Institute of Physics (AIP), 1, 2.5% American Institute of Physics (AIP) 1 publication, 2.5%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 1, 2.5% Royal Society of Chemistry (RSC) 1 publication, 2.5%
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii	Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii, 1, 2.5% Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii 1 publication, 2.5%
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KIMURA K. et al. Effect of composition on lithium-ion conductivity for perovskite-type lithium–strontium–tantalum–zirconium-oxide solid electrolytes // Ceramics International. 2016. Vol. 42. No. 4. pp. 5546-5552.

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KIMURA K., Wagatsuma K., Tojo T., Inada R., Sakurai Y. Effect of composition on lithium-ion conductivity for perovskite-type lithium–strontium–tantalum–zirconium-oxide solid electrolytes // Ceramics International. 2016. Vol. 42. No. 4. pp. 5546-5552.

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RIS Copy

TY - JOUR

DO - 10.1016/j.ceramint.2015.12.133

UR - https://doi.org/10.1016/j.ceramint.2015.12.133

TI - Effect of composition on lithium-ion conductivity for perovskite-type lithium–strontium–tantalum–zirconium-oxide solid electrolytes

T2 - Ceramics International

AU - KIMURA, KEISUKE

AU - Wagatsuma, Kota

AU - Tojo, Tomohiro

AU - Inada, Ryoji

AU - Sakurai, Yoji

PY - 2016

DA - 2016/03/01 00:00:00

PB - Elsevier

SP - 5546-5552

IS - 4

VL - 42

SN - 0272-8842

ER -

BibTex |

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BibTex Copy

@article{2016_KIMURA,

author = {KEISUKE KIMURA and Kota Wagatsuma and Tomohiro Tojo and Ryoji Inada and Yoji Sakurai},

title = {Effect of composition on lithium-ion conductivity for perovskite-type lithium–strontium–tantalum–zirconium-oxide solid electrolytes},

journal = {Ceramics International},

year = {2016},

volume = {42},

publisher = {Elsevier},

month = {mar},

url = {https://doi.org/10.1016/j.ceramint.2015.12.133},

number = {4},

pages = {5546--5552},

doi = {10.1016/j.ceramint.2015.12.133}

}

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KIMURA, KEISUKE, et al. “Effect of composition on lithium-ion conductivity for perovskite-type lithium–strontium–tantalum–zirconium-oxide solid electrolytes.” Ceramics International, vol. 42, no. 4, Mar. 2016, pp. 5546-5552. https://doi.org/10.1016/j.ceramint.2015.12.133.

Found error?

Publisher

Elsevier

Journal

Ceramics International

Quartile SCImago

Quartile WOS

Impact factor

5.2

ISSN

02728842 (Print)