Ceramics International, volume 42, issue 4, pages 5546-5552
Effect of composition on lithium-ion conductivity for perovskite-type lithium–strontium–tantalum–zirconium-oxide solid electrolytes
Publication type: Journal Article
Publication date: 2016-03-01
Journal:
Ceramics International
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 5.2
ISSN: 02728842
Materials Chemistry
Surfaces, Coatings and Films
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Process Chemistry and Technology
Abstract
We synthesized Li2x−ySr1−xTayZr1−yO3 (LSTZ, x=0.75y) with various Ta contents y=0.60, 0.70, 0.75, 0.77 and 0.8 via a conventional solid state reaction method and investigated their crystal phase, microstructure and lithium-ion conductivity. Almost single phase perovskite-type structured LSTZ was obtained at y=0.60–0.75 and their lattice sizes were increased with increasing y, indicating that Sr2+ and Zr4+ are successfully substituted by Li+ and Ta5+ with smaller ionic radii in these three samples. On the other hand, LSTZ with higher Ta contents y=0.77 and 0.8 included some impurity phases such as LiTaO3, SrTa2O6 and Sr2Ta2O7. A solid solution range for Ta into Zr site for LSTZ is expected to be y≤0.75. Both the bulk and total (bulk+grain-boundary) ionic conductivity of LSTZ monotonically increased with y from 0.60 to 0.75. Maximum bulk and total (bulk+grain-boundary) conductivities of 2.8×10−4 S cm−1 and 2.0×10−4 S cm−1 at 27 °C were obtained in LSTZ with y=0.75.
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1 publication, 2.5%
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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KIMURA K. et al. Effect of composition on lithium-ion conductivity for perovskite-type lithium–strontium–tantalum–zirconium-oxide solid electrolytes // Ceramics International. 2016. Vol. 42. No. 4. pp. 5546-5552.
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KIMURA K., Wagatsuma K., Tojo T., Inada R., Sakurai Y. Effect of composition on lithium-ion conductivity for perovskite-type lithium–strontium–tantalum–zirconium-oxide solid electrolytes // Ceramics International. 2016. Vol. 42. No. 4. pp. 5546-5552.
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TY - JOUR
DO - 10.1016/j.ceramint.2015.12.133
UR - https://doi.org/10.1016/j.ceramint.2015.12.133
TI - Effect of composition on lithium-ion conductivity for perovskite-type lithium–strontium–tantalum–zirconium-oxide solid electrolytes
T2 - Ceramics International
AU - KIMURA, KEISUKE
AU - Wagatsuma, Kota
AU - Tojo, Tomohiro
AU - Inada, Ryoji
AU - Sakurai, Yoji
PY - 2016
DA - 2016/03/01 00:00:00
PB - Elsevier
SP - 5546-5552
IS - 4
VL - 42
SN - 0272-8842
ER -
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@article{2016_KIMURA,
author = {KEISUKE KIMURA and Kota Wagatsuma and Tomohiro Tojo and Ryoji Inada and Yoji Sakurai},
title = {Effect of composition on lithium-ion conductivity for perovskite-type lithium–strontium–tantalum–zirconium-oxide solid electrolytes},
journal = {Ceramics International},
year = {2016},
volume = {42},
publisher = {Elsevier},
month = {mar},
url = {https://doi.org/10.1016/j.ceramint.2015.12.133},
number = {4},
pages = {5546--5552},
doi = {10.1016/j.ceramint.2015.12.133}
}
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MLA
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KIMURA, KEISUKE, et al. “Effect of composition on lithium-ion conductivity for perovskite-type lithium–strontium–tantalum–zirconium-oxide solid electrolytes.” Ceramics International, vol. 42, no. 4, Mar. 2016, pp. 5546-5552. https://doi.org/10.1016/j.ceramint.2015.12.133.