Ceramics International, volume 44, issue 2, pages 1538-1544
The synergistic effect of dual substitution of Al and Sb on structure and ionic conductivity of Li7La3Zr2O12 ceramic
Tiantian Yang
1
,
Yuan Li
1
,
Weiwei Wu
1
,
Zhenzhu Cao
1
,
Weiyan He
1
,
Yan-Fang Gao
1
,
Jinrong Liu
1
,
Guo-Rong Li
2
Publication type: Journal Article
Publication date: 2018-02-01
Journal:
Ceramics International
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 5.2
ISSN: 02728842
Materials Chemistry
Surfaces, Coatings and Films
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Process Chemistry and Technology
Abstract
Li 7 La 3 Zr 2 O 12 (LLZO) with cubic garnet type structure is a promising solid electrolyte. In this work, Li 6.925-3x Al x La 3 Zr 1.925 Sb 0.075 O 12 (0 ≤ x ≤ 0.1) electrolytes were prepared by conventional solid-state reaction. The influence of Sb-Al cosubstitution on the structure, microstructure and conductivity of Li 7 La 3 Zr 2 O 12 were investigated by X-ray diffraction (XRD), Raman spectroscopy, scanning electron microscopy (SEM) and impedance spectroscopy. Single cubic phase has been achieved for Li 6.925-3x Al x La 3 Zr 1.925 Sb 0.075 O 12 (x = 0–0.075). Suitable amount of Al-Sb cosubstitution accelerates densification and improves the ionic conductivity. Li 6.775 Al 0.05 La 3 Zr 1.925 Sb 0.075 O 12 exhibits highest relative densities (96.7%) and total ionic conductivity (4.10 × 10 −4 S/cm at 30 °C).
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Yang T. et al. The synergistic effect of dual substitution of Al and Sb on structure and ionic conductivity of Li7La3Zr2O12 ceramic // Ceramics International. 2018. Vol. 44. No. 2. pp. 1538-1544.
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Yang T., Li Y., Wu W., Cao Z., He W., Gao Y., Liu J., Li G. The synergistic effect of dual substitution of Al and Sb on structure and ionic conductivity of Li7La3Zr2O12 ceramic // Ceramics International. 2018. Vol. 44. No. 2. pp. 1538-1544.
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TY - JOUR
DO - 10.1016/j.ceramint.2017.10.072
UR - https://doi.org/10.1016/j.ceramint.2017.10.072
TI - The synergistic effect of dual substitution of Al and Sb on structure and ionic conductivity of Li7La3Zr2O12 ceramic
T2 - Ceramics International
AU - Yang, Tiantian
AU - Li, Yuan
AU - Wu, Weiwei
AU - Cao, Zhenzhu
AU - He, Weiyan
AU - Gao, Yan-Fang
AU - Liu, Jinrong
AU - Li, Guo-Rong
PY - 2018
DA - 2018/02/01 00:00:00
PB - Elsevier
SP - 1538-1544
IS - 2
VL - 44
SN - 0272-8842
ER -
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@article{2018_Yang,
author = {Tiantian Yang and Yuan Li and Weiwei Wu and Zhenzhu Cao and Weiyan He and Yan-Fang Gao and Jinrong Liu and Guo-Rong Li},
title = {The synergistic effect of dual substitution of Al and Sb on structure and ionic conductivity of Li7La3Zr2O12 ceramic},
journal = {Ceramics International},
year = {2018},
volume = {44},
publisher = {Elsevier},
month = {feb},
url = {https://doi.org/10.1016/j.ceramint.2017.10.072},
number = {2},
pages = {1538--1544},
doi = {10.1016/j.ceramint.2017.10.072}
}
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Yang, Tiantian, et al. “The synergistic effect of dual substitution of Al and Sb on structure and ionic conductivity of Li7La3Zr2O12 ceramic.” Ceramics International, vol. 44, no. 2, Feb. 2018, pp. 1538-1544. https://doi.org/10.1016/j.ceramint.2017.10.072.