volume 45 issue 2 pages 2492-2497

Synthesis of submicrometric VB2 powders by a boro-carbothermal reduction route

Publication typeJournal Article
Publication date2019-02-01
scimago Q1
wos Q1
SJR1.034
CiteScore9.1
Impact factor5.6
ISSN02728842, 18733956
Materials Chemistry
Surfaces, Coatings and Films
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Process Chemistry and Technology
Abstract
The submicrometric VB 2 powders are prepared at 1773 K by a boro-carbothermal reduction method using V 2 O 3 , B 4 C and C powders as the raw materials. The effects of reaction temperature and B 4 C content on the phase composition and morphology of the products are investigated. The phase transition and morphological evolution of the products are characterized by X-ray diffraction (XRD) and Field-emission scanning electron microscopy (FE-SEM). The results reveal that firstly V 2 O 3 reacts with B 4 C to generate VB 2 , VC and B 2 O 3 , and then the by-products of VC and B 2 O 3 react with C to produce VB 2 . Owing to the evaporation loss of the B 2 O 3 , excess B 4 C should be added to avoid the formation of the boron deficient phases. Only when the V 2 O 3 /B 4 C/C molar ratio is close to 1:1.26:2, the single-phase VB 2 could be prepared which has the residual carbon and oxygen contents of 0.34 wt% and 1.4 wt%, respectively. The particles of VB 2 powders obtained at 1773 K display a plate-like morphology with a size of approximately 0.1–0.8 µm.
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GOST Copy
Wu Y. et al. Synthesis of submicrometric VB2 powders by a boro-carbothermal reduction route // Ceramics International. 2019. Vol. 45. No. 2. pp. 2492-2497.
GOST all authors (up to 50) Copy
Wu Y., Zhang G., Wang Yu., Xu R., Chou K. Synthesis of submicrometric VB2 powders by a boro-carbothermal reduction route // Ceramics International. 2019. Vol. 45. No. 2. pp. 2492-2497.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1016/j.ceramint.2018.10.176
UR - https://doi.org/10.1016/j.ceramint.2018.10.176
TI - Synthesis of submicrometric VB2 powders by a boro-carbothermal reduction route
T2 - Ceramics International
AU - Wu, Yue-Dong
AU - Zhang, Guo-Hua
AU - Wang, Yu
AU - Xu, Rui
AU - Chou, Kuo-Chih
PY - 2019
DA - 2019/02/01
PB - Elsevier
SP - 2492-2497
IS - 2
VL - 45
SN - 0272-8842
SN - 1873-3956
ER -
BibTex |
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BibTex (up to 50 authors) Copy
@article{2019_Wu,
author = {Yue-Dong Wu and Guo-Hua Zhang and Yu Wang and Rui Xu and Kuo-Chih Chou},
title = {Synthesis of submicrometric VB2 powders by a boro-carbothermal reduction route},
journal = {Ceramics International},
year = {2019},
volume = {45},
publisher = {Elsevier},
month = {feb},
url = {https://doi.org/10.1016/j.ceramint.2018.10.176},
number = {2},
pages = {2492--2497},
doi = {10.1016/j.ceramint.2018.10.176}
}
MLA
Cite this
MLA Copy
Wu, Yue-Dong, et al. “Synthesis of submicrometric VB2 powders by a boro-carbothermal reduction route.” Ceramics International, vol. 45, no. 2, Feb. 2019, pp. 2492-2497. https://doi.org/10.1016/j.ceramint.2018.10.176.