Ceramics International, volume 46, issue 16, pages 24882-24886
Conductivity and structural properties of fast Ag-ion-conducting GaGeSbS–AgI glassy electrolytes
Baochen Ma
1
,
Qing Jiao Qing Jiao
2
,
Yeting Zhang
1
,
Changgui Lin Changgui Lin
1
,
Xianghua Zhang
3
,
Hongli Ma
3
,
Shixun Dai
1
,
Guang Jia
4
3
Laboratory of Glasses and Ceramics, Institute of Chemical Science, UMR CNRS 6226, University of Rennes 1, Rennes, France
|
4
Ningbo Institute of Oceanography, Ningbo, 315832, China
|
Publication type: Journal Article
Publication date: 2020-11-01
Journal:
Ceramics International
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 5.2
ISSN: 02728842
Materials Chemistry
Surfaces, Coatings and Films
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Process Chemistry and Technology
Abstract
The use of ion-conducting chalcogenide glass, a promising solid electrolyte, is encouraged at higher conductivity for all-solid-state rechargeable battery. Herein, a new quaternary glass of GaGeSbS–AgI system was successfully prepared, and its structural and electrochemical properties were investigated by XRD, Raman, and AC impendence measurement. The relatively high conductivity of 2.955 × 10−3 S/cm and low activation energy of 0.07 eV were obtained after optimized structure regulation. The short-range schematic of the glass structure was explored to determine the fast-migrating mechanism involved in conducting Ag+ ions. By controlling the proper ratio of Ga(Ge) and Sb cations, the loose and porous layer structure of [SbSxI3-x] linking by the [Ga(Ge)S4] tetrahedron was formed, resulting in the rapid transport of Ag+ ions with a reduced migration energy barrier. The current work is the first time that a sulfide solid electrolyte in quaternary glass system with desirable electrochemical characteristics was used to address energy and safety issues.
Top-30
Citations by journals
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2 publications, 28.57%
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Journal of Non-Crystalline Solids
2 publications, 28.57%
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Journal of Applied Physics
1 publication, 14.29%
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Russian Chemical Reviews
1 publication, 14.29%
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Journal of the American Ceramic Society
1 publication, 14.29%
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Citations by publishers
1
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4
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Elsevier
4 publications, 57.14%
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American Institute of Physics (AIP)
1 publication, 14.29%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 14.29%
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Wiley
1 publication, 14.29%
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- We do not take into account publications without a DOI.
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Ma B. et al. Conductivity and structural properties of fast Ag-ion-conducting GaGeSbS–AgI glassy electrolytes // Ceramics International. 2020. Vol. 46. No. 16. pp. 24882-24886.
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Ma B., Qing Jiao Q. J., Zhang Y., Changgui Lin C. L., Zhang X., Ma H., Dai S., Jia G. Conductivity and structural properties of fast Ag-ion-conducting GaGeSbS–AgI glassy electrolytes // Ceramics International. 2020. Vol. 46. No. 16. pp. 24882-24886.
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TY - JOUR
DO - 10.1016/j.ceramint.2020.06.272
UR - https://doi.org/10.1016/j.ceramint.2020.06.272
TI - Conductivity and structural properties of fast Ag-ion-conducting GaGeSbS–AgI glassy electrolytes
T2 - Ceramics International
AU - Ma, Baochen
AU - Qing Jiao, Qing Jiao
AU - Zhang, Yeting
AU - Changgui Lin, Changgui Lin
AU - Zhang, Xianghua
AU - Ma, Hongli
AU - Dai, Shixun
AU - Jia, Guang
PY - 2020
DA - 2020/11/01 00:00:00
PB - Elsevier
SP - 24882-24886
IS - 16
VL - 46
SN - 0272-8842
ER -
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@article{2020_Ma,
author = {Baochen Ma and Qing Jiao Qing Jiao and Yeting Zhang and Changgui Lin Changgui Lin and Xianghua Zhang and Hongli Ma and Shixun Dai and Guang Jia},
title = {Conductivity and structural properties of fast Ag-ion-conducting GaGeSbS–AgI glassy electrolytes},
journal = {Ceramics International},
year = {2020},
volume = {46},
publisher = {Elsevier},
month = {nov},
url = {https://doi.org/10.1016/j.ceramint.2020.06.272},
number = {16},
pages = {24882--24886},
doi = {10.1016/j.ceramint.2020.06.272}
}
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Ma, Baochen, et al. “Conductivity and structural properties of fast Ag-ion-conducting GaGeSbS–AgI glassy electrolytes.” Ceramics International, vol. 46, no. 16, Nov. 2020, pp. 24882-24886. https://doi.org/10.1016/j.ceramint.2020.06.272.