Ceramics International, volume 46, issue 16, pages 24882-24886
Conductivity and structural properties of fast Ag-ion-conducting GaGeSbS–AgI glassy electrolytes
Baochen Ma
1
,
Qing Jiao Qing Jiao
2
,
Yeting Zhang
1
,
Changgui Lin Changgui Lin
1
,
Xianghua Zhang
3
,
Hongli Ma
3
,
Shixun Dai
1
,
Guang Jia
4
3
Laboratory of Glasses and Ceramics, Institute of Chemical Science, UMR CNRS 6226, University of Rennes 1, Rennes, France
|
4
Ningbo Institute of Oceanography, Ningbo, 315832, China
|
Publication type: Journal Article
Publication date: 2020-11-01
Journal:
Ceramics International
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 5.2
ISSN: 02728842
Materials Chemistry
Surfaces, Coatings and Films
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Process Chemistry and Technology
Abstract
The use of ion-conducting chalcogenide glass, a promising solid electrolyte, is encouraged at higher conductivity for all-solid-state rechargeable battery. Herein, a new quaternary glass of GaGeSbS–AgI system was successfully prepared, and its structural and electrochemical properties were investigated by XRD, Raman, and AC impendence measurement. The relatively high conductivity of 2.955 × 10−3 S/cm and low activation energy of 0.07 eV were obtained after optimized structure regulation. The short-range schematic of the glass structure was explored to determine the fast-migrating mechanism involved in conducting Ag+ ions. By controlling the proper ratio of Ga(Ge) and Sb cations, the loose and porous layer structure of [SbSxI3-x] linking by the [Ga(Ge)S4] tetrahedron was formed, resulting in the rapid transport of Ag+ ions with a reduced migration energy barrier. The current work is the first time that a sulfide solid electrolyte in quaternary glass system with desirable electrochemical characteristics was used to address energy and safety issues.
Top-30
Citations by journals
|
1
2
|
|
|
Ceramics International
2 publications, 28.57%
|
|
|
Journal of Non-Crystalline Solids
2 publications, 28.57%
|
|
|
Journal of Applied Physics
1 publication, 14.29%
|
|
|
Russian Chemical Reviews
1 publication, 14.29%
|
|
|
Journal of the American Ceramic Society
1 publication, 14.29%
|
|
|
1
2
|
Citations by publishers
|
1
2
3
4
|
|
|
Elsevier
4 publications, 57.14%
|
|
|
American Institute of Physics (AIP)
1 publication, 14.29%
|
|
|
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 14.29%
|
|
|
Wiley
1 publication, 14.29%
|
|
|
1
2
3
4
|
- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2021,2022,2023,2024],"ids":[0,0,0,0],"codes":[0,0,0,0],"imageUrls":["","","",""],"datasets":[{"label":"Citations number","data":[2,0,1,4],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":["28.57",0,"14.29","57.14"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["Ceramics International","Journal of Non-Crystalline Solids","Journal of Applied Physics","Russian Chemical Reviews","Journal of the American Ceramic Society"],"ids":[15103,17924,11951,23802,24329],"codes":[0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/ARM4e6URKRsbRZvIF0vFis9DjxGloBjnBYJXbHmZ_medium.webp","\/storage\/images\/resized\/9Mus3KG1Tkd7Bwaurt8H3RwWh0CxRlGoO6ng9UK1_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp"],"datasets":[{"label":"","data":[2,2,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[28.57,28.57,14.29,14.29,14.29],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["Elsevier","American Institute of Physics (AIP)","Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii","Wiley"],"ids":[17,250,9422,11],"codes":[0,0,0,0],"imageUrls":["\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/ARM4e6URKRsbRZvIF0vFis9DjxGloBjnBYJXbHmZ_medium.webp","\/storage\/images\/resized\/9Mus3KG1Tkd7Bwaurt8H3RwWh0CxRlGoO6ng9UK1_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp"],"datasets":[{"label":"","data":[4,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[57.14,14.29,14.29,14.29],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartiles":{"type":"bar","data":{"show":true,"labels":[2021,2022,2023,2024],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0,0,0,0],"percentage":["0","0","0","0"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[0,0,0,0],"percentage":["0","0","0","0"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[1,0,0,2],"percentage":["14.29","0","0","28.57"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[1,0,1,2],"percentage":["14.29","0","14.29","28.57"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[0,0,0,0],"percentage":["0","0","0","0"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by SCImago per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartilesWs":{"type":"bar","data":{"show":true,"labels":[2021,2022,2023,2024],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0,0,0,0],"percentage":["0","0","0","0"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[0,0,0,0],"percentage":["0","0","0","0"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[0,0,0,1],"percentage":["0","0","0","14.29"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[2,0,1,3],"percentage":["28.57","0","14.29","42.86"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[0,0,0,0],"percentage":["0","0","0","0"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by WoS per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Ma B. et al. Conductivity and structural properties of fast Ag-ion-conducting GaGeSbS–AgI glassy electrolytes // Ceramics International. 2020. Vol. 46. No. 16. pp. 24882-24886.
GOST all authors (up to 50)
Copy
Ma B., Qing Jiao Q. J., Zhang Y., Changgui Lin C. L., Zhang X., Ma H., Dai S., Jia G. Conductivity and structural properties of fast Ag-ion-conducting GaGeSbS–AgI glassy electrolytes // Ceramics International. 2020. Vol. 46. No. 16. pp. 24882-24886.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/j.ceramint.2020.06.272
UR - https://doi.org/10.1016/j.ceramint.2020.06.272
TI - Conductivity and structural properties of fast Ag-ion-conducting GaGeSbS–AgI glassy electrolytes
T2 - Ceramics International
AU - Ma, Baochen
AU - Qing Jiao, Qing Jiao
AU - Zhang, Yeting
AU - Changgui Lin, Changgui Lin
AU - Zhang, Xianghua
AU - Ma, Hongli
AU - Dai, Shixun
AU - Jia, Guang
PY - 2020
DA - 2020/11/01 00:00:00
PB - Elsevier
SP - 24882-24886
IS - 16
VL - 46
SN - 0272-8842
ER -
Cite this
BibTex
Copy
@article{2020_Ma,
author = {Baochen Ma and Qing Jiao Qing Jiao and Yeting Zhang and Changgui Lin Changgui Lin and Xianghua Zhang and Hongli Ma and Shixun Dai and Guang Jia},
title = {Conductivity and structural properties of fast Ag-ion-conducting GaGeSbS–AgI glassy electrolytes},
journal = {Ceramics International},
year = {2020},
volume = {46},
publisher = {Elsevier},
month = {nov},
url = {https://doi.org/10.1016/j.ceramint.2020.06.272},
number = {16},
pages = {24882--24886},
doi = {10.1016/j.ceramint.2020.06.272}
}
Cite this
MLA
Copy
Ma, Baochen, et al. “Conductivity and structural properties of fast Ag-ion-conducting GaGeSbS–AgI glassy electrolytes.” Ceramics International, vol. 46, no. 16, Nov. 2020, pp. 24882-24886. https://doi.org/10.1016/j.ceramint.2020.06.272.