Ceramics International, volume 47, issue 2, pages 2123-2130

Synthesis of Ga-doped Li7La3Zr2O12 solid electrolyte with high Li+ ion conductivity

Xiao Long Huang ¹

Jianmeng Su ¹

Zhen Song ²

Tongping Xiu ³

Jun Jin ⁴

Michael E Badding ²

Z. Wen ¹

Hide authors affiliations Show authors affiliations: 4 affiliations

University of Chinese Academy of Sciences, 19 A Yuquan Rd, Shijingshan District, Beijing, 100049, PR China |

Corning Incorporated, Corning, NY 14831( USA) |

Corning Research Center China, 200 Jinsu Road, Shanghai, 201206, PR China |

⁴

CAS Key Laboratory of Materials for Energy Conversion, Shanghai Institute of Ceramics, Chinese Academy of Science, Shanghai 200050, PR China |

Publication type: Journal Article

Publication date: 2021-01-01

Elsevier

Journal: Ceramics International

Quartile SCImago

Quartile WOS

Impact factor: 5.2

ISSN: 02728842

DOI: 10.1016/j.ceramint.2020.09.047

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Materials Chemistry

Surfaces, Coatings and Films

Ceramics and Composites

Electronic, Optical and Magnetic Materials

Process Chemistry and Technology

Abstract

Garnet-type Li7La3Zr2O12 (LLZO) Li+ ion solid electrolyte is a promising candidate for next generation high-safety solid-state batteries. Ga-doped LLZO exhibits excellent Li+ ion conductivity, higher than 1 × 10−3 S cm−1. In this research, the doping amount of Ga, the calcination temperature of Ga-LLZO primary powders, the sintering conditions and the evolution of grains are explored to demonstrate the optimum parameters to obtain a highly conductive ceramics reproducibly via conventional solid-state reaction methods under ambient air sintering atmosphere. Cubic LLZO phase is obtained for Li6.4Ga0.2La3Zr2O12 powder calcined at low temperature 850 °C. In addition, ceramic pellets sintered at 1100 °C for 320 min using this powder have relative densities higher than 94% and conductivities higher than 1.2 × 10−3 S cm−1 at 25 °C.

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ACS Applied Energy Materials	ACS Applied Energy Materials, 2, 4.88% ACS Applied Energy Materials 2 publications, 4.88%
Journal of Energy Storage	Journal of Energy Storage, 2, 4.88% Journal of Energy Storage 2 publications, 4.88%
Journal of the European Ceramic Society	Journal of the European Ceramic Society, 2, 4.88% Journal of the European Ceramic Society 2 publications, 4.88%
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Electrochimica Acta	Electrochimica Acta, 1, 2.44% Electrochimica Acta 1 publication, 2.44%
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Citations by publishers

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Elsevier	Elsevier, 24, 58.54% Elsevier 24 publications, 58.54%
Wiley	Wiley, 5, 12.2% Wiley 5 publications, 12.2%
American Chemical Society (ACS)	American Chemical Society (ACS), 4, 9.76% American Chemical Society (ACS) 4 publications, 9.76%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 2, 4.88% Multidisciplinary Digital Publishing Institute (MDPI) 2 publications, 4.88%
Frontiers Media S.A.	Frontiers Media S.A., 1, 2.44% Frontiers Media S.A. 1 publication, 2.44%
Springer Nature	Springer Nature, 1, 2.44% Springer Nature 1 publication, 2.44%
IOP Publishing	IOP Publishing, 1, 2.44% IOP Publishing 1 publication, 2.44%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 1, 2.44% Royal Society of Chemistry (RSC) 1 publication, 2.44%
OAE Publishing Inc.	OAE Publishing Inc., 1, 2.44% OAE Publishing Inc. 1 publication, 2.44%
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii	Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii, 1, 2.44% Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii 1 publication, 2.44%
	5 10 15 20 25

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Huang X. L. et al. Synthesis of Ga-doped Li7La3Zr2O12 solid electrolyte with high Li+ ion conductivity // Ceramics International. 2021. Vol. 47. No. 2. pp. 2123-2130.

GOST all authors (up to 50) Copy

Huang X. L., Su J., Song Z., Xiu T., Jin J., Badding M. E., Wen Z. Synthesis of Ga-doped Li7La3Zr2O12 solid electrolyte with high Li+ ion conductivity // Ceramics International. 2021. Vol. 47. No. 2. pp. 2123-2130.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1016/j.ceramint.2020.09.047

UR - https://doi.org/10.1016/j.ceramint.2020.09.047

TI - Synthesis of Ga-doped Li7La3Zr2O12 solid electrolyte with high Li+ ion conductivity

T2 - Ceramics International

AU - Huang, Xiao Long

AU - Su, Jianmeng

AU - Song, Zhen

AU - Xiu, Tongping

AU - Jin, Jun

AU - Badding, Michael E

AU - Wen, Z.

PY - 2021

DA - 2021/01/01 00:00:00

PB - Elsevier

SP - 2123-2130

IS - 2

VL - 47

SN - 0272-8842

ER -

BibTex |

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BibTex Copy

@article{2021_Huang,

author = {Xiao Long Huang and Jianmeng Su and Zhen Song and Tongping Xiu and Jun Jin and Michael E Badding and Z. Wen},

title = {Synthesis of Ga-doped Li7La3Zr2O12 solid electrolyte with high Li+ ion conductivity},

journal = {Ceramics International},

year = {2021},

volume = {47},

publisher = {Elsevier},

month = {jan},

url = {https://doi.org/10.1016/j.ceramint.2020.09.047},

number = {2},

pages = {2123--2130},

doi = {10.1016/j.ceramint.2020.09.047}

}

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MLA Copy

Huang, Xiao Long, et al. “Synthesis of Ga-doped Li7La3Zr2O12 solid electrolyte with high Li+ ion conductivity.” Ceramics International, vol. 47, no. 2, Jan. 2021, pp. 2123-2130. https://doi.org/10.1016/j.ceramint.2020.09.047.

Found error?

Publisher

Elsevier

Journal

Ceramics International

Quartile SCImago

Quartile WOS

Impact factor

5.2

ISSN

02728842 (Print)