Ceramics International, volume 47, issue 12, pages 17034-17040
Lanthanide doping of Li7La3-xMxZr2O12 (M=Sm, Dy, Er, Yb; x=0.1–1.0) and dopant size effect on the electrochemical properties
Publication type: Journal Article
Publication date: 2021-06-01
Journal:
Ceramics International
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 5.2
ISSN: 02728842
Materials Chemistry
Surfaces, Coatings and Films
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Process Chemistry and Technology
Abstract
Lithium-ion batteries, as one of the energy storage devices, has attracted much attention due to its remarkable characteristics. However, they pose safety challenges because of their liquid electrolytes. Solid electrolytes are one of the key candidates to tackle the safety issues in Li-ion batteries. As a solid electrolyte, garnet-type Li 7 La 3 Zr 2 O 12 is a promising candidate with its high stability against lithium metal and wide electrochemical window among its counterparts. But, the ionic conductivity is yet to be compared with liquid electrolytes. Hence, doping is still the common strategy to adjust the ionic conductivities. Despite the fact that doping with various elements is well-documented, Lanthanide group element doping is not thoroughly investigated. This research is to study the synthesis of garnet-type Li 7 La 3-x M x Zr 2 O 12 (M = Sm, Dy, Er, Yb; x = 0.0–1.0) novel compositions to enlighten the effect of lanthanide group element doping as a function of ionic radius. Results showed that increasing dopant ionic radius improves densification, diminishes Li-ion conduction and, except Yb case, expands the lattice. However, impurity phases formed when the solubility limit is reached, has overall a positive impact on Li-ion conduction. The highest ionic conductivity (0.15 mS/cm) and lowest activation energy (0.18 eV) without impurity phases were obtained from Yb doped LLZO. It was also found that the presence of LiDyO 2 improves the ionic conductivity to 0.16 mS/cm.
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Abdulai M., Dermenci K. B., Turan S. Lanthanide doping of Li7La3-xMxZr2O12 (M=Sm, Dy, Er, Yb; x=0.1–1.0) and dopant size effect on the electrochemical properties // Ceramics International. 2021. Vol. 47. No. 12. pp. 17034-17040.
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Abdulai M., Dermenci K. B., Turan S. Lanthanide doping of Li7La3-xMxZr2O12 (M=Sm, Dy, Er, Yb; x=0.1–1.0) and dopant size effect on the electrochemical properties // Ceramics International. 2021. Vol. 47. No. 12. pp. 17034-17040.
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TY - JOUR
DO - 10.1016/j.ceramint.2021.03.010
UR - https://doi.org/10.1016/j.ceramint.2021.03.010
TI - Lanthanide doping of Li7La3-xMxZr2O12 (M=Sm, Dy, Er, Yb; x=0.1–1.0) and dopant size effect on the electrochemical properties
T2 - Ceramics International
AU - Abdulai, Musah
AU - Dermenci, Kamil Burak
AU - Turan, Servet
PY - 2021
DA - 2021/06/01 00:00:00
PB - Elsevier
SP - 17034-17040
IS - 12
VL - 47
SN - 0272-8842
ER -
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@article{2021_Abdulai,
author = {Musah Abdulai and Kamil Burak Dermenci and Servet Turan},
title = {Lanthanide doping of Li7La3-xMxZr2O12 (M=Sm, Dy, Er, Yb; x=0.1–1.0) and dopant size effect on the electrochemical properties},
journal = {Ceramics International},
year = {2021},
volume = {47},
publisher = {Elsevier},
month = {jun},
url = {https://doi.org/10.1016/j.ceramint.2021.03.010},
number = {12},
pages = {17034--17040},
doi = {10.1016/j.ceramint.2021.03.010}
}
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Abdulai, Musah, et al. “Lanthanide doping of Li7La3-xMxZr2O12 (M=Sm, Dy, Er, Yb; x=0.1–1.0) and dopant size effect on the electrochemical properties.” Ceramics International, vol. 47, no. 12, Jun. 2021, pp. 17034-17040. https://doi.org/10.1016/j.ceramint.2021.03.010.