Ceramics International, volume 48, issue 18, pages 25949-25957
Boosting lithium-ion transport capability of LAGP/PPO composite solid electrolyte via component regulation from ‘Ceramics-in-Polymer’ to ‘Polymer-in-Ceramics'
Zhenhao Huang
1
,
Jie Li
1
,
Lin-xin Li
1
,
Huimin Xu
1
,
Changseok Han
1
,
Ming-Quan Liu
2
,
Jun Xiang
3
,
Xiangqian Shen
1
,
Mao-xiang Jing
1
Publication type: Journal Article
Publication date: 2022-09-01
Journal:
Ceramics International
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 5.2
ISSN: 02728842
Materials Chemistry
Surfaces, Coatings and Films
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Process Chemistry and Technology
Abstract
The design and regulation of the ion transport channels in the polymer electrolyte is an important means to improve the lithium ion transport behavior of the electrolyte. In this work, we for the first time combined the high ionic conductive inorganic ceramic electrolyte Li 1.5 Al 0.5 Ge 1.5 (PO 4 ) 3 (LAGP) with flexible polypropylene oxide (PPO) polymer electrolyte to synthesize a high-filling LAGP/PPO composite solid electrolyte film and regulated the ion transport channels from ‘Ceramics-in-Polymer’ mode to ‘Polymer-in-Ceramics' mode by optimizing the ratio of LAGP vs. PPO. The results reveal that when the LAGP content <40%, the electrolyte belongs to ‘LAGP-in-PPO’, and then changes to ‘PPO-in-LAGP’ when the LAGP content exceeds 40%. Compared with ‘LAGP-in-PPO’, the ‘PPO-in-LAGP’ shows better comprehensive properties, especially for the 75% LAGP-filled PPO electrolyte, the room-temperature ionic conductivity is as high as 3.46 × 10 −4 Scm −1 , the ion migration number and voltage stable window reach 0.83 and 4.78 V respectively. This high-filled composite electrolyte possesses high tensile stress of 40 MPa with a strain of 46% and withstands working environment up to 200 °C. The NCM622/Li solid-state battery composed of this electrolyte also presents good rate and cycle performances with a capacity retention of 80% after 230 cycles at 0.3C because of its high ion transport capability and good inhibition of lithium dendrites. This composite structural design is expected to develop high-performance solid-state electrolytes suitable for high-voltage solid-state lithium batteries.
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Huang Z. et al. Boosting lithium-ion transport capability of LAGP/PPO composite solid electrolyte via component regulation from ‘Ceramics-in-Polymer’ to ‘Polymer-in-Ceramics' // Ceramics International. 2022. Vol. 48. No. 18. pp. 25949-25957.
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Huang Z., Li J., Li L., Xu H., Han C., Liu M., Xiang J., Shen X., Jing M. Boosting lithium-ion transport capability of LAGP/PPO composite solid electrolyte via component regulation from ‘Ceramics-in-Polymer’ to ‘Polymer-in-Ceramics' // Ceramics International. 2022. Vol. 48. No. 18. pp. 25949-25957.
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TY - JOUR
DO - 10.1016/j.ceramint.2022.05.274
UR - https://doi.org/10.1016/j.ceramint.2022.05.274
TI - Boosting lithium-ion transport capability of LAGP/PPO composite solid electrolyte via component regulation from ‘Ceramics-in-Polymer’ to ‘Polymer-in-Ceramics'
T2 - Ceramics International
AU - Huang, Zhenhao
AU - Li, Jie
AU - Li, Lin-xin
AU - Xu, Huimin
AU - Han, Changseok
AU - Liu, Ming-Quan
AU - Xiang, Jun
AU - Shen, Xiangqian
AU - Jing, Mao-xiang
PY - 2022
DA - 2022/09/01 00:00:00
PB - Elsevier
SP - 25949-25957
IS - 18
VL - 48
SN - 0272-8842
ER -
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@article{2022_Huang,
author = {Zhenhao Huang and Jie Li and Lin-xin Li and Huimin Xu and Changseok Han and Ming-Quan Liu and Jun Xiang and Xiangqian Shen and Mao-xiang Jing},
title = {Boosting lithium-ion transport capability of LAGP/PPO composite solid electrolyte via component regulation from ‘Ceramics-in-Polymer’ to ‘Polymer-in-Ceramics'},
journal = {Ceramics International},
year = {2022},
volume = {48},
publisher = {Elsevier},
month = {sep},
url = {https://doi.org/10.1016/j.ceramint.2022.05.274},
number = {18},
pages = {25949--25957},
doi = {10.1016/j.ceramint.2022.05.274}
}
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Huang, Zhenhao, et al. “Boosting lithium-ion transport capability of LAGP/PPO composite solid electrolyte via component regulation from ‘Ceramics-in-Polymer’ to ‘Polymer-in-Ceramics'.” Ceramics International, vol. 48, no. 18, Sep. 2022, pp. 25949-25957. https://doi.org/10.1016/j.ceramint.2022.05.274.
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