Ceramics International, volume 48, issue 21, pages 31755-31762
On the way to understand the keys for the stabilization of the conductive phase in doped- NASICON-type materials
1
INQUISUR -Dpto. Química -Universidad Nacional del Sur, Av. Alem 1253, Bahía Blanca, Provincia de Buenos Aires, Argentina
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2
INTEQUI-CONICET, FQBF-UNSL, Alte. Brown 1455, 5700, San Luis, Argentina
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Publication type: Journal Article
Publication date: 2022-11-01
Journal:
Ceramics International
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 5.2
ISSN: 02728842
Materials Chemistry
Surfaces, Coatings and Films
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Process Chemistry and Technology
Abstract
A family of doped-NASICON-type structures according to the chemical compositions: Li 1.2 Zr 1.9 M 0.1 (PO 4 ) 3 [with M = Ca 2+ , Mg 2+ , Zn 2+ ]; Li 1.1 Zr 1.9 Y 0.1 (PO 4 ) 3 and Li 1.0 Zr 1.9 Ce 0.1 (PO 4 ) 3 have been synthesized by solid state reaction. The modification on the thermal treatment proposed in this work makes possible to obtain a high purity phase confirmed by XRD, SEM, microRaman-confocal and FTIR. Rietveld refinement evidences how the LZP lattice parameters are affected by each of those five different dopant cations incorporated into the pristine structure. Impedance spectroscopy proves how the relationship radius - charge of each dopant-ion affects the ionic conductivity. Unravelling that the partial replacement of Zr 4+ in the LZP by a dopant improves the conductivity behavior. When the dopant cation has a lower charge and a larger size than the Zr 4+ the developed structure favours the lithium-ion mobility at room temperature and the lithium conductivity increases.
Top-30
Citations by journals
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Ceramics International
1 publication, 50%
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Russian Chemical Reviews
1 publication, 50%
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Citations by publishers
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Elsevier
1 publication, 50%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 50%
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Terny S. et al. On the way to understand the keys for the stabilization of the conductive phase in doped- NASICON-type materials // Ceramics International. 2022. Vol. 48. No. 21. pp. 31755-31762.
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Terny S., López C. A., Narda G., Frechero M. On the way to understand the keys for the stabilization of the conductive phase in doped- NASICON-type materials // Ceramics International. 2022. Vol. 48. No. 21. pp. 31755-31762.
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TY - JOUR
DO - 10.1016/j.ceramint.2022.07.102
UR - https://doi.org/10.1016/j.ceramint.2022.07.102
TI - On the way to understand the keys for the stabilization of the conductive phase in doped- NASICON-type materials
T2 - Ceramics International
AU - Terny, S
AU - López, Carlos A
AU - Narda, G.E.
AU - Frechero, M.A.
PY - 2022
DA - 2022/11/01 00:00:00
PB - Elsevier
SP - 31755-31762
IS - 21
VL - 48
SN - 0272-8842
ER -
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@article{2022_Terny,
author = {S Terny and Carlos A López and G.E. Narda and M.A. Frechero},
title = {On the way to understand the keys for the stabilization of the conductive phase in doped- NASICON-type materials},
journal = {Ceramics International},
year = {2022},
volume = {48},
publisher = {Elsevier},
month = {nov},
url = {https://doi.org/10.1016/j.ceramint.2022.07.102},
number = {21},
pages = {31755--31762},
doi = {10.1016/j.ceramint.2022.07.102}
}
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Terny, S., et al. “On the way to understand the keys for the stabilization of the conductive phase in doped- NASICON-type materials.” Ceramics International, vol. 48, no. 21, Nov. 2022, pp. 31755-31762. https://doi.org/10.1016/j.ceramint.2022.07.102.