Ceramics International, volume 48, issue 24, pages 36961-36967
Low-temperature fabrication of NASICON-type LATP with superior ionic conductivity
Shao-Peng Shen
1
,
Geng Tang
1
,
Hongji Li
1
,
Liang Zhang
2
,
Jin-Chi Zheng
2
,
Yanping Luo
2
,
Jian Ping Yue
1
,
Yongzheng Shi
1
,
Zhe Chen
1
2
Electric Power Research Institute, State Grid Xinjiang Electric Power Company Limited, Urumqi, 830011, China
|
Publication type: Journal Article
Publication date: 2022-12-01
Journal:
Ceramics International
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 5.2
ISSN: 02728842
Materials Chemistry
Surfaces, Coatings and Films
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Process Chemistry and Technology
Abstract
NASICON-type Li 1.3 Al 0.3 Ti 1.7 (PO 4 ) 3 (LATP) has attracted much attention as a fast lithium-ion conductor for all-solid-state lithium-based batteries. However, the large grain-boundary resistance and high sintering temperature above 950 °C for pure LATP electrolytes hinder their practical application in lithium-based batteries. Here, a low-temperature preparation approach for the superionic conductor LATP electrolyte with sintering aids is proposed. By introducing sintering aids Li 3 PO 4 , LiBO 2 ·0.3H 2 O, and binary 0.32Li 3 PO 4 -0.68LiBO 2 ·0.3H 2 O, LATP-based pellets can be fabricated at optimized sintering temperatures below 900 °C. The resultant LATP-based pellets maintain a high relative density and homogeneous microstructure, which arises from the sintering aid to facilitate the grain rearrangement and fill the interstices between grains. The LATP pellets using sintering aid Li 3 PO 4 achieve a high ionic conductivity of 5.2 × 10 −4 S cm −1 at a low temperature of 800 °C, 7.3 times that (7.1 × 10 −5 S cm −1 ) of pure LATP pellets sintered at 950 °C, which demonstrates the effectiveness of low-temperature preparation approach to reducing the preparation cost and optimizing the ionic conductivity of LATP-based electrolytes.
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Shen S. et al. Low-temperature fabrication of NASICON-type LATP with superior ionic conductivity // Ceramics International. 2022. Vol. 48. No. 24. pp. 36961-36967.
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Shen S., Tang G., Li H., Zhang L., Zheng J., Luo Y., Yue J. P., Shi Y., Chen Z. Low-temperature fabrication of NASICON-type LATP with superior ionic conductivity // Ceramics International. 2022. Vol. 48. No. 24. pp. 36961-36967.
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TY - JOUR
DO - 10.1016/j.ceramint.2022.08.264
UR - https://doi.org/10.1016/j.ceramint.2022.08.264
TI - Low-temperature fabrication of NASICON-type LATP with superior ionic conductivity
T2 - Ceramics International
AU - Shen, Shao-Peng
AU - Tang, Geng
AU - Li, Hongji
AU - Zhang, Liang
AU - Zheng, Jin-Chi
AU - Luo, Yanping
AU - Yue, Jian Ping
AU - Shi, Yongzheng
AU - Chen, Zhe
PY - 2022
DA - 2022/12/01 00:00:00
PB - Elsevier
SP - 36961-36967
IS - 24
VL - 48
SN - 0272-8842
ER -
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@article{2022_Shen,
author = {Shao-Peng Shen and Geng Tang and Hongji Li and Liang Zhang and Jin-Chi Zheng and Yanping Luo and Jian Ping Yue and Yongzheng Shi and Zhe Chen},
title = {Low-temperature fabrication of NASICON-type LATP with superior ionic conductivity},
journal = {Ceramics International},
year = {2022},
volume = {48},
publisher = {Elsevier},
month = {dec},
url = {https://doi.org/10.1016/j.ceramint.2022.08.264},
number = {24},
pages = {36961--36967},
doi = {10.1016/j.ceramint.2022.08.264}
}
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Shen, Shao-Peng, et al. “Low-temperature fabrication of NASICON-type LATP with superior ionic conductivity.” Ceramics International, vol. 48, no. 24, Dec. 2022, pp. 36961-36967. https://doi.org/10.1016/j.ceramint.2022.08.264.