Ceramics International, volume 50, issue 7, pages 12450-12458
Effect of addition of LiAlSiO4 on microstructure, phase composition, and electrical properties of Li1.3Al0.3Ti1.7(PO4)3–based solid electrolyte
K Kwatek
1
,
W. Ślubowska-Walkusz
1
,
J.L. Nowiński
1
,
Agnieszka Teresa Krawczynska
2
,
Isabel Sobrados
3
,
Virginia Diez-Gómez
3
,
J. Sanz
,
Jesus Sanz
3
3
National Research Council, The Materials Science Institute of Madrid (ICMM CSIC), 28049, Madrid, Spain
|
Publication type: Journal Article
Publication date: 2024-04-01
Journal:
Ceramics International
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 5.2
ISSN: 02728842
Materials Chemistry
Surfaces, Coatings and Films
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Process Chemistry and Technology
Abstract
Li1.3Al0.3Ti1.7(PO4)3 (LATP) NASICON-type ceramic, due to its high bulk conductivity, is believed to be one of the most appropriate material for application as solid electrolyte in all-solid-state lithium-ion batteries. However, its highly resistant grain boundaries strongly limit the total ionic conductivity. Therefore, in this work, an attempt has been made to overcome this problem by introducing a Li-ion conducting additive LiAlSiO4 (LASO) to LATP base matrix in order to provide more conduction paths for lithium ions between grains. The properties of Li1.3Al0.3Ti1.7(PO4)3–xLiAlSiO4 (0.02 ≤ x ≤ 0.1) composite system were studied by means of: high-temperature X-ray powder diffractometry (HTXRD), 6Li, 27Al, and 31P magic angle spinning nuclear magnetic resonance spectroscopy (MAS NMR), scanning electron microscopy (SEM), and impedance spectroscopy (IS) methods. The obtained ceramic LATP–LASO materials exhibited high values of bulk conductivity, above 10−3 S/cm, and good total conductivity, exceeding 10−4 S/cm. The factors responsible for the enhancement, but also for the deterioration of total conductivity, i.e. microstructure and grain boundaries, are identified and discussed in this work.
Top-30
Citations by journals
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Russian Chemical Reviews
1 publication, 100%
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Citations by publishers
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 100%
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Kwatek K. et al. Effect of addition of LiAlSiO4 on microstructure, phase composition, and electrical properties of Li1.3Al0.3Ti1.7(PO4)3–based solid electrolyte // Ceramics International. 2024. Vol. 50. No. 7. pp. 12450-12458.
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Kwatek K., Ślubowska-Walkusz W., Nowiński J., Krawczynska A. T., Sobrados I., Diez-Gómez V., Sanz J., Sanz J. Effect of addition of LiAlSiO4 on microstructure, phase composition, and electrical properties of Li1.3Al0.3Ti1.7(PO4)3–based solid electrolyte // Ceramics International. 2024. Vol. 50. No. 7. pp. 12450-12458.
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TY - JOUR
DO - 10.1016/j.ceramint.2024.01.154
UR - https://linkinghub.elsevier.com/retrieve/pii/S0272884224001688
TI - Effect of addition of LiAlSiO4 on microstructure, phase composition, and electrical properties of Li1.3Al0.3Ti1.7(PO4)3–based solid electrolyte
T2 - Ceramics International
AU - Kwatek, K
AU - Ślubowska-Walkusz, W.
AU - Nowiński, J.L.
AU - Krawczynska, Agnieszka Teresa
AU - Sobrados, Isabel
AU - Diez-Gómez, Virginia
AU - Sanz, Jesus
AU - Sanz, J.
PY - 2024
DA - 2024/04/01 00:00:00
PB - Elsevier
SP - 12450-12458
IS - 7
VL - 50
SN - 0272-8842
ER -
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@article{2024_Kwatek,
author = {K Kwatek and W. Ślubowska-Walkusz and J.L. Nowiński and Agnieszka Teresa Krawczynska and Isabel Sobrados and Virginia Diez-Gómez and Jesus Sanz and J. Sanz},
title = {Effect of addition of LiAlSiO4 on microstructure, phase composition, and electrical properties of Li1.3Al0.3Ti1.7(PO4)3–based solid electrolyte},
journal = {Ceramics International},
year = {2024},
volume = {50},
publisher = {Elsevier},
month = {apr},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0272884224001688},
number = {7},
pages = {12450--12458},
doi = {10.1016/j.ceramint.2024.01.154}
}
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Kwatek, K., et al. “Effect of addition of LiAlSiO4 on microstructure, phase composition, and electrical properties of Li1.3Al0.3Ti1.7(PO4)3–based solid electrolyte.” Ceramics International, vol. 50, no. 7, Apr. 2024, pp. 12450-12458. https://linkinghub.elsevier.com/retrieve/pii/S0272884224001688.