Ceramics International, volume 50, issue 8, pages 13943-13948
To the limit of the remagnetization energy barrier for the Dy3+-based single ion magnet in the apatite ceramic matrix
Kazin P. E.
1
,
Zykin Mikhail A
1
,
Karpov Maxim A
1
,
Vasiliev Alexander V.
1
,
Sharifullin Timur Z
1
,
Eliseev A. A.
1
,
Eliseev Artem A
1
,
2
Max Planck Institute for Solid State Research, Heisenbergstrasse 1, 70569, Stuttgart, Germany
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Publication type: Journal Article
Publication date: 2024-04-01
Journal:
Ceramics International
Quartile SCImago
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Quartile WOS
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Impact factor: 5.2
ISSN: 02728842
Materials Chemistry
Surfaces, Coatings and Films
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Process Chemistry and Technology
Abstract
Doping of the (Sr,Ba)10(PO4)6(OH)2 apatite ceramics with a small quantity of Dy2O3 was studied. Formation of the Dy3+ containing high-energy single-ion magnet (SIM) in the apatite structure was confirmed. Partial replacement of Ba for Sr in the structure resulted in a regular increase of the remagnetization energy barrier Ueff from 1043 to 1119 cm−1, while the solubility of Dy3+ in the compound dropped drastically. Ueff followed simple relations with the alkaline-earth metal cation size and the compound composition, highlighting predictability of SIM parameters.
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Kazin P. E. et al. To the limit of the remagnetization energy barrier for the Dy3+-based single ion magnet in the apatite ceramic matrix // Ceramics International. 2024. Vol. 50. No. 8. pp. 13943-13948.
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Kazin P. E., Zykin M. A., Karpov M. A., Vasiliev A. V., Sharifullin T. Z., Eliseev A. A., Eliseev A. A., Kremer R. K., Dinnebier R. E., Jansen M. To the limit of the remagnetization energy barrier for the Dy3+-based single ion magnet in the apatite ceramic matrix // Ceramics International. 2024. Vol. 50. No. 8. pp. 13943-13948.
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TY - JOUR
DO - 10.1016/j.ceramint.2024.01.311
UR - https://doi.org/10.1016%2Fj.ceramint.2024.01.311
TI - To the limit of the remagnetization energy barrier for the Dy3+-based single ion magnet in the apatite ceramic matrix
T2 - Ceramics International
AU - Kazin, P. E.
AU - Zykin, Mikhail A
AU - Karpov, Maxim A
AU - Vasiliev, Alexander V.
AU - Sharifullin, Timur Z
AU - Eliseev, A. A.
AU - Eliseev, Artem A
AU - Kremer, Reinhard K.
AU - Dinnebier, Robert E.
AU - Jansen, Martin
PY - 2024
DA - 2024/04/01 00:00:00
PB - Elsevier
SP - 13943-13948
IS - 8
VL - 50
SN - 0272-8842
ER -
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@article{2024_Kazin,
author = {P. E. Kazin and Mikhail A Zykin and Maxim A Karpov and Alexander V. Vasiliev and Timur Z Sharifullin and A. A. Eliseev and Artem A Eliseev and Reinhard K. Kremer and Robert E. Dinnebier and Martin Jansen},
title = {To the limit of the remagnetization energy barrier for the Dy3+-based single ion magnet in the apatite ceramic matrix},
journal = {Ceramics International},
year = {2024},
volume = {50},
publisher = {Elsevier},
month = {apr},
url = {https://doi.org/10.1016%2Fj.ceramint.2024.01.311},
number = {8},
pages = {13943--13948},
doi = {10.1016/j.ceramint.2024.01.311}
}
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Kazin, P. E., et al. “To the limit of the remagnetization energy barrier for the Dy3+-based single ion magnet in the apatite ceramic matrix.” Ceramics International, vol. 50, no. 8, Apr. 2024, pp. 13943-13948. https://doi.org/10.1016%2Fj.ceramint.2024.01.311.