NMR evidence of supercooled water formation during gas hydrate dissociation below the melting point of ice
Тип публикации: Journal Article
Дата публикации: 2012-03-01
scimago Q1
wos Q2
БС1
SJR: 0.84
CiteScore: 7.9
Impact factor: 4.3
ISSN: 00092509, 18734405
General Chemistry
General Chemical Engineering
Industrial and Manufacturing Engineering
Applied Mathematics
Краткое описание
Preliminary results are presented on the use of nuclear magnetic resonance (NMR) relaxation spectroscopy for analysis of water phase transformations during dissociation of gas hydrate dispersions below 273 K. Freon-12 hydrates formed a cubic structure II were used for model studies without need for high pressure. Freon hydrates were formed from micron-sized water droplets with an average radius of about 5 μm dispersed in polyethylsiloxane fluid (PES-5). This research demonstrates the possibility of using NMR relaxation spectroscopy to study phase transformations of water in gas hydrate systems at temperatures below 273 K, including the region of their metastable states on the P–T phase diagram below the ice–hydrate–gas equilibrium pressure.
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ГОСТ
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Melnikov V. et al. NMR evidence of supercooled water formation during gas hydrate dissociation below the melting point of ice // Chemical Engineering Science. 2012. Vol. 71. pp. 573-577.
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Melnikov V., Nesterov A. N., Podenko L. S., Reshetnikov A. M., Shalamov V. V. NMR evidence of supercooled water formation during gas hydrate dissociation below the melting point of ice // Chemical Engineering Science. 2012. Vol. 71. pp. 573-577.
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TY - JOUR
DO - 10.1016/j.ces.2011.11.039
UR - https://doi.org/10.1016/j.ces.2011.11.039
TI - NMR evidence of supercooled water formation during gas hydrate dissociation below the melting point of ice
T2 - Chemical Engineering Science
AU - Melnikov, V.P.
AU - Nesterov, A N
AU - Podenko, L S
AU - Reshetnikov, A M
AU - Shalamov, V V
PY - 2012
DA - 2012/03/01
PB - Elsevier
SP - 573-577
VL - 71
SN - 0009-2509
SN - 1873-4405
ER -
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BibTex (до 50 авторов)
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@article{2012_Melnikov,
author = {V.P. Melnikov and A N Nesterov and L S Podenko and A M Reshetnikov and V V Shalamov},
title = {NMR evidence of supercooled water formation during gas hydrate dissociation below the melting point of ice},
journal = {Chemical Engineering Science},
year = {2012},
volume = {71},
publisher = {Elsevier},
month = {mar},
url = {https://doi.org/10.1016/j.ces.2011.11.039},
pages = {573--577},
doi = {10.1016/j.ces.2011.11.039}
}