Prediction of Solubility of Acetylene in Organic Solvents over a Wide Range of Temperature and Pressure
Publication type: Journal Article
Publication date: 2023-07-01
scimago Q1
wos Q2
SJR: 0.840
CiteScore: 7.9
Impact factor: 4.3
ISSN: 00092509, 18734405
General Chemistry
General Chemical Engineering
Industrial and Manufacturing Engineering
Applied Mathematics
Abstract
Acetylene has been used directly to synthesize various vinyl compounds. To avoid the explosion risk of gas-phase acetylene during the reaction, it is more reliable to dissolve acetylene in the solvent(s) first, and then make it react in the liquid phase. Accordingly, the solubility of acetylene is the most essential information for the solvent selection and the reaction process design. This work makes efforts to accurately predict the acetylene solubility in many organic solvents over a wide range of temperatures and pressures by optimizing two parameters in COSMO-RS based on solvent classification by σ-profile analysis. The model predictions are evaluated by 1173 solubility data of acetylene and the average absolute relative deviation is 13.0%. This established theoretical method provides a large number of solubility data of acetylene for reference to guide the liquid-phase reaction process design, where the synthesis of N-vinylpyrrolidone is chosen as a case illustration.
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Metrics
9
Total citations:
9
Citations from 2025:
2
(25%)
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GOST
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Mu Y. et al. Prediction of Solubility of Acetylene in Organic Solvents over a Wide Range of Temperature and Pressure // Chemical Engineering Science. 2023. Vol. 276. p. 118824.
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Mu Y., Yan L., Chu B., Shen Z., Fan J., Cheng Y. Prediction of Solubility of Acetylene in Organic Solvents over a Wide Range of Temperature and Pressure // Chemical Engineering Science. 2023. Vol. 276. p. 118824.
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RIS
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TY - JOUR
DO - 10.1016/j.ces.2023.118824
UR - https://doi.org/10.1016/j.ces.2023.118824
TI - Prediction of Solubility of Acetylene in Organic Solvents over a Wide Range of Temperature and Pressure
T2 - Chemical Engineering Science
AU - Mu, Yuguang
AU - Yan, Le
AU - Chu, Bozhao
AU - Shen, Zhong
AU - Fan, Jiahe
AU - Cheng, Yi
PY - 2023
DA - 2023/07/01
PB - Elsevier
SP - 118824
VL - 276
SN - 0009-2509
SN - 1873-4405
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2023_Mu,
author = {Yuguang Mu and Le Yan and Bozhao Chu and Zhong Shen and Jiahe Fan and Yi Cheng},
title = {Prediction of Solubility of Acetylene in Organic Solvents over a Wide Range of Temperature and Pressure},
journal = {Chemical Engineering Science},
year = {2023},
volume = {276},
publisher = {Elsevier},
month = {jul},
url = {https://doi.org/10.1016/j.ces.2023.118824},
pages = {118824},
doi = {10.1016/j.ces.2023.118824}
}
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