Separation of 44Ti from proton irradiated scandium by using solid-phase extraction chromatography and design of 44Ti/44Sc generator system
Тип публикации: Journal Article
Дата публикации: 2016-12-01
scimago Q1
wos Q1
БС1
SJR: 0.731
CiteScore: 7.3
Impact factor: 4
ISSN: 00219673, 18733778
PubMed ID:
27903405
Organic Chemistry
Biochemistry
General Medicine
Analytical Chemistry
Краткое описание
Scandium-44g (half-life 3.97h [1]) shows promise for positron emission tomography (PET) imaging of longer biological processes than that of the current gold standard, 18F, due to its favorable decay parameters. One source of 44gSc is the long-lived parent nuclide 44Ti (half-life 60.0 a). A 44Ti/44gSc generator would have the ability to provide radionuclidically pure 44gSc on a daily basis. The production of 44Ti via the 45Sc(p,2n) reaction requires high proton beam currents and long irradiation times. Recovery and purification of no-carrier added (nca) 44Ti from scandium metal targets involves complex separation chemistry. In this study, separation systems based on solid phase extraction chromatography were investigated, including branched diglycolamide (BDGA) resin and hydroxamate based ZR resin. Results indicate that ZR resin in HCl media represents an effective 44Ti/44gSc separation system.
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Radchenko V. et al. Separation of 44Ti from proton irradiated scandium by using solid-phase extraction chromatography and design of 44Ti/44Sc generator system // Journal of Chromatography A. 2016. Vol. 1477. pp. 39-46.
ГОСТ со всеми авторами (до 50)
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Radchenko V., Meyer C., Engle J. W., Naranjo C. M., Unc G. A., Mastren T., Brugh M., R. Birnbaum E., John K., Nortier F., Fassbender M. Separation of 44Ti from proton irradiated scandium by using solid-phase extraction chromatography and design of 44Ti/44Sc generator system // Journal of Chromatography A. 2016. Vol. 1477. pp. 39-46.
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TY - JOUR
DO - 10.1016/j.chroma.2016.11.047
UR - https://doi.org/10.1016/j.chroma.2016.11.047
TI - Separation of 44Ti from proton irradiated scandium by using solid-phase extraction chromatography and design of 44Ti/44Sc generator system
T2 - Journal of Chromatography A
AU - Radchenko, V.
AU - Meyer, Catherine
AU - Engle, Jonathan W.
AU - Naranjo, C M
AU - Unc, G A
AU - Mastren, T
AU - Brugh, M
AU - R. Birnbaum, E.
AU - John, K.-D.
AU - Nortier, F.M
AU - Fassbender, M.E.
PY - 2016
DA - 2016/12/01
PB - Elsevier
SP - 39-46
VL - 1477
PMID - 27903405
SN - 0021-9673
SN - 1873-3778
ER -
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BibTex (до 50 авторов)
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@article{2016_Radchenko,
author = {V. Radchenko and Catherine Meyer and Jonathan W. Engle and C M Naranjo and G A Unc and T Mastren and M Brugh and E. R. Birnbaum and K.-D. John and F.M Nortier and M.E. Fassbender},
title = {Separation of 44Ti from proton irradiated scandium by using solid-phase extraction chromatography and design of 44Ti/44Sc generator system},
journal = {Journal of Chromatography A},
year = {2016},
volume = {1477},
publisher = {Elsevier},
month = {dec},
url = {https://doi.org/10.1016/j.chroma.2016.11.047},
pages = {39--46},
doi = {10.1016/j.chroma.2016.11.047}
}