Advances in Colloid and Interface Science, volume 246, pages 196-216
Porous structure of ion exchange membranes investigated by various techniques
N. A. Kononenko
1
,
V. V. Nikonenko
1
,
DANIEL A. GRANDE
2
,
C. Larchet
2
,
L. Dammak
2
,
M Fomenko
1
,
Yu Volfkovich
3
Publication type: Journal Article
Publication date: 2017-08-01
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 15.6
ISSN: 00018686
Physical and Theoretical Chemistry
Colloid and Surface Chemistry
Surfaces and Interfaces
Abstract
A comparative review of various techniques is provided: mercury intrusion porosimetry, nitrogen sorption porosimetry, differential scanning calorimetry (DSC)-based thermoporosimetry, and standard contact porosimetry (SCP), which allows determining pore volume distribution versus pore radius/water binding energy in ion-exchange membranes (IEMs). IEMs in the swollen state have a labile structure involving micro-, meso- and macropores, whose size is a function of the external water vapor pressure. For such materials, the most appropriate methods for quantifying their porosity are DSC and SCP. Especially significant information is given by the SCP method allowing measuring porosimetric curves in a very large pore size range from 1 to 105nm. Experimental results of water distribution in homogeneous and heterogeneous commercial and modified IEMs are presented. The effect of various factors on water distribution is reviewed, i.e. nature of polymeric matrix and functional groups, method for membrane preparation, membrane ageing. A special attention is given to the effect of membrane modification by embedding nanoparticles in their structure. The porosimetric curves are considered along with the results of electrochemical characterization involving the measurements of membrane conductivity, as well as diffusion and electroosmotic permeability. It is shown that addition of nanoparticles may lead to either increase or decrease of water content in IEMs, different ranges of pore size being affected. Hybrid membranes modified with hydrated zirconium dioxide exhibit much higher permselectivity in comparison with the pristine membranes. The diversity of the responses of membrane properties to their modification allows for formation of membranes suitable for fuel cells, electrodialysis or other applications.
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35
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Kononenko N. A. et al. Porous structure of ion exchange membranes investigated by various techniques // Advances in Colloid and Interface Science. 2017. Vol. 246. pp. 196-216.
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Kononenko N. A., Nikonenko V. V., GRANDE D. A., Larchet C., Dammak L., Fomenko M., Volfkovich Yu. Porous structure of ion exchange membranes investigated by various techniques // Advances in Colloid and Interface Science. 2017. Vol. 246. pp. 196-216.
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TY - JOUR
DO - 10.1016/j.cis.2017.05.007
UR - https://linkinghub.elsevier.com/retrieve/pii/S0001868617301793
TI - Porous structure of ion exchange membranes investigated by various techniques
T2 - Advances in Colloid and Interface Science
AU - Kononenko, N. A.
AU - Nikonenko, V. V.
AU - GRANDE, DANIEL A.
AU - Larchet, C.
AU - Dammak, L.
AU - Fomenko, M
AU - Volfkovich, Yu
PY - 2017
DA - 2017/08/01 00:00:00
PB - Elsevier
SP - 196-216
VL - 246
SN - 0001-8686
ER -
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@article{2017_Kononenko,
author = {N. A. Kononenko and V. V. Nikonenko and DANIEL A. GRANDE and C. Larchet and L. Dammak and M Fomenko and Yu Volfkovich},
title = {Porous structure of ion exchange membranes investigated by various techniques},
journal = {Advances in Colloid and Interface Science},
year = {2017},
volume = {246},
publisher = {Elsevier},
month = {aug},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0001868617301793},
pages = {196--216},
doi = {10.1016/j.cis.2017.05.007}
}