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Colloids and Interface Science Communications, volume 46, pages 100575

Interfacial self-assembly of ultrathin polydiacetylene/graphene oxide nanocomposites: A new method for synergetic enhancement of surface charge transfer without doping

Gusarova Elizaveta A ¹

Zvyagina Alexandra I ¹

Kuzmina Natalia V

Shabatin Andrey V ¹

Tameev Alexey R

Aleksandrov Alexey E

Aleksandrov Alexey ¹

Kuzmina Natalia P. ¹

Averin Alexey A ¹

Tameev Alexey ¹

Kalinina Maria A ¹

Hide authors affiliations Show authors affiliations: 1 affiliation

Frumkin Institute of Physical Chemistry and Electrochemistry RAS, Leninsky prospect, 31, bldg. 4, Moscow 119071, Russia |

Publication type: Journal Article

Publication date: 2022-01-01

Elsevier

Journal: Colloids and Interface Science Communications

Quartile SCImago

Quartile WOS

Impact factor: 4.5

ISSN: 22150382

DOI: 10.1016/j.colcom.2021.100575

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Materials Chemistry

Surfaces, Coatings and Films

Physical and Theoretical Chemistry

Colloid and Surface Chemistry

Biotechnology

Abstract

A new method for interfacial self-assembly of graphene oxide (GO) and 10,12-pentacosadiynoic acid into nanometer-thick light-absorbing films exhibiting synergetic enhancement of conductive properties is developed. The blue form of polydiacetylene (PDA) nanopatches with a thickness of 5–10 nm is stabilized through the interactions between GO and PDA. The hole-transferring polymer decreases contact resistance in the GO sublayer through “healing” the gaps between the GO nanosheets. The separation of electron-hole pairs at the PDA/GO interface under applied electric field leads to a doping-free enhancement of the in-plane surface conductivity by 6 orders of magnitude up to 46.4 S·cm −1 with respect to those of individual components. These PDA/GO nanocomposites were applied as ultrathin diodes/photodiodes in a solar cell by creating a PDA/C 60 heterojunction and a light-induced cross-layer charge transfer. The method can be adapted to a variety of polymerizable light-absorbing surfactants for fabricating GO-based nanohybrids for photoelectronics. • Graphene oxide (GO)/diacetylene nanofilms are formed via interfacial self-assembly. • Light-absorbing polymer is a conductive “healer” of defects in the GO sublayer. • In-plane surface conductivity of the nanofilms is enhanced by 10 6 without doping. • GO/polydiacetylene nanofilm can operate as an ultrathin diode/photodiode.

By date By citations

Citations by journals

	1 2
Colloid Journal	Colloid Journal, 2, 28.57% Colloid Journal 2 publications, 28.57%
Langmuir	Langmuir, 1, 14.29% Langmuir 1 publication, 14.29%
Colloids and Interface Science Communications	Colloids and Interface Science Communications, 1, 14.29% Colloids and Interface Science Communications 1 publication, 14.29%
Journal of Applied Polymer Science	Journal of Applied Polymer Science, 1, 14.29% Journal of Applied Polymer Science 1 publication, 14.29%
New Journal of Chemistry	New Journal of Chemistry, 1, 14.29% New Journal of Chemistry 1 publication, 14.29%
	1 2

Citations by publishers

	1 2
Pleiades Publishing	Pleiades Publishing, 2, 28.57% Pleiades Publishing 2 publications, 28.57%
American Chemical Society (ACS)	American Chemical Society (ACS), 1, 14.29% American Chemical Society (ACS) 1 publication, 14.29%
Elsevier	Elsevier, 1, 14.29% Elsevier 1 publication, 14.29%
Wiley	Wiley, 1, 14.29% Wiley 1 publication, 14.29%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 1, 14.29% Royal Society of Chemistry (RSC) 1 publication, 14.29%
	1 2

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GOST Copy

Gusarova E. A. et al. Interfacial self-assembly of ultrathin polydiacetylene/graphene oxide nanocomposites: A new method for synergetic enhancement of surface charge transfer without doping // Colloids and Interface Science Communications. 2022. Vol. 46. p. 100575.

GOST all authors (up to 50) Copy

Gusarova E. A., Zvyagina A. I., Kuzmina N. V., Shabatin A. V., Aleksandrov A. E., Tameev A. R., Aleksandrov A., Kuzmina N. P., Averin A. A., Tameev A., Kalinina M. A. Interfacial self-assembly of ultrathin polydiacetylene/graphene oxide nanocomposites: A new method for synergetic enhancement of surface charge transfer without doping // Colloids and Interface Science Communications. 2022. Vol. 46. p. 100575.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1016/j.colcom.2021.100575

UR - https://doi.org/10.1016%2Fj.colcom.2021.100575

TI - Interfacial self-assembly of ultrathin polydiacetylene/graphene oxide nanocomposites: A new method for synergetic enhancement of surface charge transfer without doping

T2 - Colloids and Interface Science Communications

AU - Gusarova, Elizaveta A

AU - Zvyagina, Alexandra I

AU - Kuzmina, Natalia V

AU - Shabatin, Andrey V

AU - Aleksandrov, Alexey E

AU - Tameev, Alexey R

AU - Aleksandrov, Alexey

AU - Kuzmina, Natalia P.

AU - Averin, Alexey A

AU - Tameev, Alexey

AU - Kalinina, Maria A

PY - 2022

DA - 2022/01/01 00:00:00

PB - Elsevier

SP - 100575

VL - 46

SN - 2215-0382

ER -

BibTex

Cite this

BibTex Copy

@article{2022_Gusarova,

author = {Elizaveta A Gusarova and Alexandra I Zvyagina and Natalia V Kuzmina and Andrey V Shabatin and Alexey E Aleksandrov and Alexey R Tameev and Alexey Aleksandrov and Natalia P. Kuzmina and Alexey A Averin and Alexey Tameev and Maria A Kalinina},

title = {Interfacial self-assembly of ultrathin polydiacetylene/graphene oxide nanocomposites: A new method for synergetic enhancement of surface charge transfer without doping},

journal = {Colloids and Interface Science Communications},

year = {2022},

volume = {46},

publisher = {Elsevier},

month = {jan},

url = {https://doi.org/10.1016%2Fj.colcom.2021.100575},

pages = {100575},

doi = {10.1016/j.colcom.2021.100575}

}

Found error?

Publisher

Elsevier

Journal

Colloids and Interface Science Communications

Quartile SCImago

Quartile WOS

Impact factor

4.5

ISSN

22150382 (Electronic)

Labs

A group of supramolecular hybrid materials in the Bioelectrochemistry Laboratory

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