Colloids and Surfaces A: Physicochemical and Engineering Aspects

, volume 553 , pages 368-377

Solubilization of azo-dye-modiﬁed isatin derivative by amphiphilic carboxyresorcinarenes: The effect of macrocycle structure on the supramolecular association

Victor V. Syakaev ¹

Julia Morozova ²

Yana V Shalaeva ²

Vladimir V Zobov ¹

Vladimir F. Mironov ²

Alexander I Konovalov ¹

Andrei V Bogdanov ²

Alina M Ermakova ²

A. D. Voloshina ¹

I. R. Nizameev ^{1, 3}

M K Kadirov ¹

Hide authors affiliations Show authors affiliations: 3 affiliations

Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of RAS, Arbuzov str. 8, 420088 Kazan, Russian Federation

A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences

Kazan Scientific Center of the Russian Academy of Sciences

Kazan Federal University, Kremlevskaya st. 18, 420008 Kazan, Russian Federation |

Kazan National Research Technical University named after A. N. Tupolev – KAI, K. Marx str. 10, 420111 Kazan, Russian Federation |

Publication type: Journal Article

Publication date: 2018-09-01

Elsevier

Colloids and Surfaces A: Physicochemical and Engineering Aspects

scimago Q1

wos Q2

SJR: 0.944

CiteScore: 9.6

Impact factor: 5.4

ISSN: 09277757, 18734359

DOI: 10.1016/j.colsurfa.2018.05.078

Copy DOI

Colloid and Surface Chemistry

Abstract

Here we present the consecutive study of colloid systems formed by novel isatin derivative as compound with high pharmacological potential and series of carboxyresorcinarenes. The azo-modiﬁed isatin derivative bearing ammonium moiety (I-3) was synthesized and its antimicrobial activity was investigated. To increase its solubility the solubilization experiment using amphiphilic carboxyresorcinarenes, characterized by low hemolytic activity, was carried out. The I-3 – macrocycles systems were studied by NMR, UV–vis, DLS and TEM. The FT PGSE and 2D NOESY NMR methods demonstrated, that solubilization of I-3 is caused by the incorporation of its molecules in the hydrophobic part of the macrocycles associates. Herewith the loading efficiency of I-3 into the macrocycles associates was reached of 20–30% due to the change of the volume of hydrophobic part of associates by varying the length and structure of hydrophobic substituents of macrocyclic amphiphiles.

Found

3 citations

Babaev Vasily

PhD in Chemistry, associate professor

81 publications, 925 citations

h-index: 17

A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences

Research interests

Mass Spectrometry

3 citations

Babaeva Olga

PhD in Chemistry

56 publications, 436 citations

h-index: 12

A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences

Research interests

Organic Chemistry

Physical Chemistry

1 citation

Arsenyev Maxim

🥼 🤝

PhD in Chemistry

94 publications, 803 citations, 2 reviews

h-index: 17

G. A. Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences

Lobachevsky State University of Nizhny Novgorod

Research interests

Photopolymerization

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GOST |

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GOST Copy

Syakaev V. V. et al. Solubilization of azo-dye-modiﬁed isatin derivative by amphiphilic carboxyresorcinarenes: The effect of macrocycle structure on the supramolecular association // Colloids and Surfaces A: Physicochemical and Engineering Aspects. 2018. Vol. 553. pp. 368-377.

GOST all authors (up to 50) Copy

Syakaev V. V., Morozova J., Shalaeva Y. V., Zobov V. V., Mironov V. F., Konovalov A. I., Bogdanov A. V., Ermakova A. M., Voloshina A. D., Nizameev I. R., Kadirov M. K. Solubilization of azo-dye-modiﬁed isatin derivative by amphiphilic carboxyresorcinarenes: The effect of macrocycle structure on the supramolecular association // Colloids and Surfaces A: Physicochemical and Engineering Aspects. 2018. Vol. 553. pp. 368-377.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1016/j.colsurfa.2018.05.078

UR - https://doi.org/10.1016/j.colsurfa.2018.05.078

TI - Solubilization of azo-dye-modiﬁed isatin derivative by amphiphilic carboxyresorcinarenes: The effect of macrocycle structure on the supramolecular association

T2 - Colloids and Surfaces A: Physicochemical and Engineering Aspects

AU - Syakaev, Victor V.

AU - Morozova, Julia

AU - Shalaeva, Yana V

AU - Zobov, Vladimir V

AU - Mironov, Vladimir F.

AU - Konovalov, Alexander I

AU - Bogdanov, Andrei V

AU - Ermakova, Alina M

AU - Voloshina, A. D.

AU - Nizameev, I. R.

AU - Kadirov, M K

PY - 2018

DA - 2018/09/01

PB - Elsevier

SP - 368-377

VL - 553

SN - 0927-7757

SN - 1873-4359

ER -

BibTex

Cite this

BibTex (up to 50 authors) Copy

@article{2018_Syakaev,

author = {Victor V. Syakaev and Julia Morozova and Yana V Shalaeva and Vladimir V Zobov and Vladimir F. Mironov and Alexander I Konovalov and Andrei V Bogdanov and Alina M Ermakova and A. D. Voloshina and I. R. Nizameev and M K Kadirov},

title = {Solubilization of azo-dye-modiﬁed isatin derivative by amphiphilic carboxyresorcinarenes: The effect of macrocycle structure on the supramolecular association},

journal = {Colloids and Surfaces A: Physicochemical and Engineering Aspects},

year = {2018},

volume = {553},

publisher = {Elsevier},

month = {sep},

url = {https://doi.org/10.1016/j.colsurfa.2018.05.078},

pages = {368--377},

doi = {10.1016/j.colsurfa.2018.05.078}

}

Publisher

Elsevier

Journal

Colloids and Surfaces A: Physicochemical and Engineering Aspects

scimago Q1

wos Q2

SJR

0.944

CiteScore

9.6

Impact factor

5.4

ISSN

09277757 (Print)

18734359 (Electronic)

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