Synthesis and photophysical properties of colloids fabricated by the layer-by-layer polyelectrolyte assembly onto Eu(III) complex as a core
Rustem Zairov
1
,
Margit Gruner
2
,
Alsu Ibragimova
1
,
Dmitry Tatarinov
1
,
Irek Nizameyev
1
,
Vitaly Yanilkin
1
,
M K Kadirov
1
,
Vladimir Mironov
1
,
1
2
Institute of Organic Chemistry, Technical University, Bergshtrasse street, 66, 01069 Dresden, Germany
|
Publication type: Journal Article
Publication date: 2011-11-01
scimago Q1
wos Q1
SJR: 0.978
CiteScore: 11.8
Impact factor: 5.6
ISSN: 09277765, 18734367
PubMed ID:
21835599
Physical and Theoretical Chemistry
General Medicine
Colloid and Surface Chemistry
Biotechnology
Surfaces and Interfaces
Abstract
The luminescent colloids have been synthesized through the layer-by-layer assembly of poly(sodium 4-styrenesulfonate) (PSS) and polyethyleneimine (PEI) onto the luminescent core. The latter has been obtained by the reprecipitation of complex Eu[(TTA)(3)1] (where TTA(-) and 1 are thenoyltrifluoroacetonate and 2-(5-chlorophenyl-2-hydroxy)-2-phenylethenyl-bis-(2-methoxyphenyl)phosphine oxide, respectively) from organic solvent to aqueous solution. The variation of Eu(III) complexes indicates the role of the complex core in the development of such core-shell colloids. Complex Eu[(TTA)(3)1] is most convenient precursor of Eu-doped luminescent nanocomposites. The fluorometric measurements at each step of the layer-by-layer polyelectrolyte assembly onto Eu[(TTA)(3)1] core, at various pHs and additives reveal the quenching of Eu-centered luminescence as a result of the interfacial interaction of the core and the dye. The AFM images and electrochemical behavior of PSS-(PEI-PSS)(n)-Eu[(TTA)(3)1] colloids deposited on the surface indicate the stability of the polyelectrolyte multilayer in the dried state.
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Mustafina A. R. et al. Synthesis and photophysical properties of colloids fabricated by the layer-by-layer polyelectrolyte assembly onto Eu(III) complex as a core // Colloids and Surfaces B: Biointerfaces. 2011. Vol. 88. No. 1. pp. 490-496.
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Mustafina A. R., Zairov R., Gruner M., Ibragimova A., Tatarinov D., Nizameyev I., Nastapova N. V., Yanilkin V., Kadirov M. K., Mironov V., Konovalov A. N. Synthesis and photophysical properties of colloids fabricated by the layer-by-layer polyelectrolyte assembly onto Eu(III) complex as a core // Colloids and Surfaces B: Biointerfaces. 2011. Vol. 88. No. 1. pp. 490-496.
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TY - JOUR
DO - 10.1016/j.colsurfb.2011.07.039
UR - https://doi.org/10.1016/j.colsurfb.2011.07.039
TI - Synthesis and photophysical properties of colloids fabricated by the layer-by-layer polyelectrolyte assembly onto Eu(III) complex as a core
T2 - Colloids and Surfaces B: Biointerfaces
AU - Mustafina, Asiya R.
AU - Zairov, Rustem
AU - Gruner, Margit
AU - Ibragimova, Alsu
AU - Tatarinov, Dmitry
AU - Nizameyev, Irek
AU - Nastapova, Natalya V.
AU - Yanilkin, Vitaly
AU - Kadirov, M K
AU - Mironov, Vladimir
AU - Konovalov, Alexander N.
PY - 2011
DA - 2011/11/01
PB - Elsevier
SP - 490-496
IS - 1
VL - 88
PMID - 21835599
SN - 0927-7765
SN - 1873-4367
ER -
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BibTex (up to 50 authors)
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@article{2011_Mustafina,
author = {Asiya R. Mustafina and Rustem Zairov and Margit Gruner and Alsu Ibragimova and Dmitry Tatarinov and Irek Nizameyev and Natalya V. Nastapova and Vitaly Yanilkin and M K Kadirov and Vladimir Mironov and Alexander N. Konovalov},
title = {Synthesis and photophysical properties of colloids fabricated by the layer-by-layer polyelectrolyte assembly onto Eu(III) complex as a core},
journal = {Colloids and Surfaces B: Biointerfaces},
year = {2011},
volume = {88},
publisher = {Elsevier},
month = {nov},
url = {https://doi.org/10.1016/j.colsurfb.2011.07.039},
number = {1},
pages = {490--496},
doi = {10.1016/j.colsurfb.2011.07.039}
}
Cite this
MLA
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Mustafina, Asiya R., et al. “Synthesis and photophysical properties of colloids fabricated by the layer-by-layer polyelectrolyte assembly onto Eu(III) complex as a core.” Colloids and Surfaces B: Biointerfaces, vol. 88, no. 1, Nov. 2011, pp. 490-496. https://doi.org/10.1016/j.colsurfb.2011.07.039.