том 1046 страницы 42-48

A computational (DFT) study on aza-Claisen rearrangement: Effect of temperature, solvent and substitution on activation barrier

Тип публикацииJournal Article
Дата публикации2014-10-01
scimago Q2
wos Q3
white level БС3
SJR0.439
CiteScore4.7
Impact factor2.8
ISSN2210271X
Biochemistry
Physical and Theoretical Chemistry
Condensed Matter Physics
Краткое описание
The effect of temperature, solvent and substitution on aza-Claisen rearrangement has been studied using DFT. A contour diagram of potential energy surface (PES) of transition state (TS) is represented to explain the variation of activation barrier of aza-Claisen rearrangements for different substitutions. A comparison of aza-Claisen rearrangement with aza-cope, oxy- and thio-Claisen rearrangement has also been presented. The possible causes have been explored for the drastic conditions required for aza-Claisen rearrangement.
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ГОСТ |
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Debnath S., Mondal S. A computational (DFT) study on aza-Claisen rearrangement: Effect of temperature, solvent and substitution on activation barrier // Computational and Theoretical Chemistry. 2014. Vol. 1046. pp. 42-48.
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Debnath S., Mondal S. A computational (DFT) study on aza-Claisen rearrangement: Effect of temperature, solvent and substitution on activation barrier // Computational and Theoretical Chemistry. 2014. Vol. 1046. pp. 42-48.
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TY - JOUR
DO - 10.1016/j.comptc.2014.07.010
UR - https://doi.org/10.1016/j.comptc.2014.07.010
TI - A computational (DFT) study on aza-Claisen rearrangement: Effect of temperature, solvent and substitution on activation barrier
T2 - Computational and Theoretical Chemistry
AU - Debnath, Sudarshan
AU - Mondal, Shovan
PY - 2014
DA - 2014/10/01
PB - Elsevier
SP - 42-48
VL - 1046
SN - 2210-271X
ER -
BibTex
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BibTex (до 50 авторов) Скопировать
@article{2014_Debnath,
author = {Sudarshan Debnath and Shovan Mondal},
title = {A computational (DFT) study on aza-Claisen rearrangement: Effect of temperature, solvent and substitution on activation barrier},
journal = {Computational and Theoretical Chemistry},
year = {2014},
volume = {1046},
publisher = {Elsevier},
month = {oct},
url = {https://doi.org/10.1016/j.comptc.2014.07.010},
pages = {42--48},
doi = {10.1016/j.comptc.2014.07.010}
}
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