Inhibition properties and adsorption behavior of imidazole and 2-phenyl-2-imidazoline on AA5052 in 1.0M HCl solution
Publication type: Journal Article
Publication date: 2014-06-01
scimago Q1
wos Q1
SJR: 2.189
CiteScore: 14.1
Impact factor: 8.5
ISSN: 0010938X, 18790496
General Chemistry
General Chemical Engineering
General Materials Science
Abstract
• IM and 2-PI show corrosion inhibition for AA5052 in HCl solution. • Synergistic effect between IM and 2-PI is observed and its mechanism is assumed. • Adsorption properties are estimated using Δ G ads 0 , Δ H ads 0 and E a , respectively. • Adsorption structures and inhibition mechanism for AA5052 are proposed. The inhibition behavior of imidazole (IM) and 2-phenyl-2-imidazoline (2-PI) for AA5052 was investigated by weight loss, electrochemical, contact angle measurements and scanning electron microscopy. The results show that IM and 2-PI can inhibit the corrosion of AA5052 and the inhibition efficiency of 2-PI is higher. The adsorption properties of them are estimated using Δ G ads 0 , Δ H ads 0 and E a . The results reveal that the adsorption processes are exothermic reactions mainly by a monolayer chemisorption mechanism, and follow Langmuir adsorption isotherm. The differences of the monolayer adsorption structure between IM and 2-PI on AA5052 surface are analyzed, and the inhibition mechanisms are proposed.
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He X. et al. Inhibition properties and adsorption behavior of imidazole and 2-phenyl-2-imidazoline on AA5052 in 1.0M HCl solution // Corrosion Science. 2014. Vol. 83. pp. 124-136.
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He X., Jiang Y., Li C., Wang W., Hou B., Wu L. Inhibition properties and adsorption behavior of imidazole and 2-phenyl-2-imidazoline on AA5052 in 1.0M HCl solution // Corrosion Science. 2014. Vol. 83. pp. 124-136.
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TY - JOUR
DO - 10.1016/j.corsci.2014.02.004
UR - https://doi.org/10.1016/j.corsci.2014.02.004
TI - Inhibition properties and adsorption behavior of imidazole and 2-phenyl-2-imidazoline on AA5052 in 1.0M HCl solution
T2 - Corrosion Science
AU - He, Xinkuai
AU - Jiang, Yumei
AU - Li, Chen
AU - Wang, Weichun
AU - Hou, Bailong
AU - Wu, Luye
PY - 2014
DA - 2014/06/01
PB - Elsevier
SP - 124-136
VL - 83
SN - 0010-938X
SN - 1879-0496
ER -
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@article{2014_He,
author = {Xinkuai He and Yumei Jiang and Chen Li and Weichun Wang and Bailong Hou and Luye Wu},
title = {Inhibition properties and adsorption behavior of imidazole and 2-phenyl-2-imidazoline on AA5052 in 1.0M HCl solution},
journal = {Corrosion Science},
year = {2014},
volume = {83},
publisher = {Elsevier},
month = {jun},
url = {https://doi.org/10.1016/j.corsci.2014.02.004},
pages = {124--136},
doi = {10.1016/j.corsci.2014.02.004}
}