Experimental chloride ion affinities and theoretical predictions for the absolute heats of formation of SiCl2 and SiClF
Publication type: Journal Article
Publication date: 2004-05-01
scimago Q2
wos Q2
SJR: 0.546
CiteScore: 5.9
Impact factor: 3.1
ISSN: 00092614, 18734448
Physical and Theoretical Chemistry
General Physics and Astronomy
Abstract
The chloride ion affinities of SiCl2 and SiClF have been determined from threshold energy collision-induced dissociation in a flowing afterglow-triple quadrupole instrument. Values of 244.8 ± 13.9 and 205.4 ± 8.5 kJ/mol were obtained for the chloride ion affinities of SiCl2 and SiClF. The measured chloride ion affinities can be used in thermochemical cycles with calculated data to give heats of formation of the halosilylenes SiCl2 and SiClF of −146.8 ± 20 and −385.0 ± 20 kJ/mol. G2 predictions for the heats of formation of the two silylenes are in good agreement with those derived from our experimental measurements.
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Poutsma J. C., Schroeder O. E., Squires R. H. Experimental chloride ion affinities and theoretical predictions for the absolute heats of formation of SiCl2 and SiClF // Chemical Physics Letters. 2004. Vol. 389. No. 4-6. pp. 433-437.
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Poutsma J. C., Schroeder O. E., Squires R. H. Experimental chloride ion affinities and theoretical predictions for the absolute heats of formation of SiCl2 and SiClF // Chemical Physics Letters. 2004. Vol. 389. No. 4-6. pp. 433-437.
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TY - JOUR
DO - 10.1016/j.cplett.2004.03.137
UR - https://doi.org/10.1016/j.cplett.2004.03.137
TI - Experimental chloride ion affinities and theoretical predictions for the absolute heats of formation of SiCl2 and SiClF
T2 - Chemical Physics Letters
AU - Poutsma, John C
AU - Schroeder, Olivia E
AU - Squires, Robert H.
PY - 2004
DA - 2004/05/01
PB - Elsevier
SP - 433-437
IS - 4-6
VL - 389
SN - 0009-2614
SN - 1873-4448
ER -
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BibTex (up to 50 authors)
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@article{2004_Poutsma,
author = {John C Poutsma and Olivia E Schroeder and Robert H. Squires},
title = {Experimental chloride ion affinities and theoretical predictions for the absolute heats of formation of SiCl2 and SiClF},
journal = {Chemical Physics Letters},
year = {2004},
volume = {389},
publisher = {Elsevier},
month = {may},
url = {https://doi.org/10.1016/j.cplett.2004.03.137},
number = {4-6},
pages = {433--437},
doi = {10.1016/j.cplett.2004.03.137}
}
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Poutsma, John C., et al. “Experimental chloride ion affinities and theoretical predictions for the absolute heats of formation of SiCl2 and SiClF.” Chemical Physics Letters, vol. 389, no. 4-6, May. 2004, pp. 433-437. https://doi.org/10.1016/j.cplett.2004.03.137.