Chemical Physics Letters

, volume 490 , issue 4-6 , pages 148-153

Regioselective electrochemical reduction of 2,4-dichlorobiphenyl – Distinct standard reduction potentials for carbon–chlorine bonds using convolution potential sweep voltammetry

Azhagumuthu Muthukrishnan ¹

M. V. Sangaranarayanan ¹

Vadim P Boyarskiy ²

I A Boyarskaya ²

Hide authors affiliations Show authors affiliations: 2 affiliations

Department of Chemistry, Indian Institute of Technology Madras,Chennai – 600 036,India |

Department of Chemistry, St. Petersburg State University, Universitetskii pr. 26, St. Petersburg 198504, Russia |

Publication type: Journal Article

Publication date: 2010-04-01

Elsevier

Chemical Physics Letters

scimago Q2

wos Q2

SJR: 0.546

CiteScore: 5.9

Impact factor: 3.1

ISSN: 00092614, 18734448

DOI: 10.1016/j.cplett.2010.03.042

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Physical and Theoretical Chemistry

General Physics and Astronomy

Abstract

The reductive cleavage of carbon–chlorine bonds in 2,4-dichlorobiphenyl (PCB-7) is investigated using the convolution potential sweep voltammetry and quantum chemical calculations. The potential dependence of the logarithmic rate constant is non-linear which indicates the validity of Marcus–Hush theory of quadratic activation-driving force relationship. The ortho-chlorine of the 2,4-dichlorobiphenyl gets reduced first as inferred from the quantum chemical calculations and bulk electrolysis. The standard reduction potentials pertaining to the ortho-chlorine of 2,4-dichlorobiphenyl and that corresponding to para chlorine of the 4-chlorobiphenyl have been estimated.

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Muthukrishnan A. et al. Regioselective electrochemical reduction of 2,4-dichlorobiphenyl – Distinct standard reduction potentials for carbon–chlorine bonds using convolution potential sweep voltammetry // Chemical Physics Letters. 2010. Vol. 490. No. 4-6. pp. 148-153.

GOST all authors (up to 50) Copy

Muthukrishnan A., Sangaranarayanan M. V., Boyarskiy V. P., Boyarskaya I. A. Regioselective electrochemical reduction of 2,4-dichlorobiphenyl – Distinct standard reduction potentials for carbon–chlorine bonds using convolution potential sweep voltammetry // Chemical Physics Letters. 2010. Vol. 490. No. 4-6. pp. 148-153.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1016/j.cplett.2010.03.042

UR - https://linkinghub.elsevier.com/retrieve/pii/S0009261410004239

TI - Regioselective electrochemical reduction of 2,4-dichlorobiphenyl – Distinct standard reduction potentials for carbon–chlorine bonds using convolution potential sweep voltammetry

T2 - Chemical Physics Letters

AU - Muthukrishnan, Azhagumuthu

AU - Sangaranarayanan, M. V.

AU - Boyarskiy, Vadim P

AU - Boyarskaya, I A

PY - 2010

DA - 2010/04/01

PB - Elsevier

SP - 148-153

IS - 4-6

VL - 490

SN - 0009-2614

SN - 1873-4448

ER -

BibTex |

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BibTex (up to 50 authors) Copy

@article{2010_Muthukrishnan,

author = {Azhagumuthu Muthukrishnan and M. V. Sangaranarayanan and Vadim P Boyarskiy and I A Boyarskaya},

title = {Regioselective electrochemical reduction of 2,4-dichlorobiphenyl – Distinct standard reduction potentials for carbon–chlorine bonds using convolution potential sweep voltammetry},

journal = {Chemical Physics Letters},

year = {2010},

volume = {490},

publisher = {Elsevier},

month = {apr},

url = {https://linkinghub.elsevier.com/retrieve/pii/S0009261410004239},

number = {4-6},

pages = {148--153},

doi = {10.1016/j.cplett.2010.03.042}

}

MLA

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Muthukrishnan, Azhagumuthu, et al. “Regioselective electrochemical reduction of 2,4-dichlorobiphenyl – Distinct standard reduction potentials for carbon–chlorine bonds using convolution potential sweep voltammetry.” Chemical Physics Letters, vol. 490, no. 4-6, Apr. 2010, pp. 148-153. https://linkinghub.elsevier.com/retrieve/pii/S0009261410004239.