Paramagnetic centers in detonation nanodiamonds studied by CW and pulse EPR
Тип публикации: Journal Article
Дата публикации: 2010-06-01
SCImago Q2
WOS Q2
БС2
SJR: 0.5
CiteScore: 5.8
Impact factor: 2.9
ISSN: 00092614, 18734448
Physical and Theoretical Chemistry
General Physics and Astronomy
Краткое описание
Dispersed detonation nanodiamonds have been studied by continuous-wave (CW) and pulse EPR techniques. The spectrum of bulk radicals ( g = 2.0025 ± 0.0002, a Lorentz line shape with Δ H pp = 0.95 ± 0.05 mT) dominated in CW EPR and prevented to record spectra from other paramagnetic species. The pulse EPR-spectrum was the superposition of the distorted P1-center spectrum with parameters ( g = 2.0025, A xx = 2.57 mT, A yy = 3.08 mT, A zz = 4.07 mT), the H1-center spectrum ( g = 2.0028) and the single line ( g = 2.0025, Δ H pp = 0.40 ± 0.05 mT) from other centers which may be assigned to surface radicals. The concentration of P1-centers has been estimated by CW EPR as 2 ± 1 ppm N.
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Fionov A. S. et al. Paramagnetic centers in detonation nanodiamonds studied by CW and pulse EPR // Chemical Physics Letters. 2010. Vol. 493. No. 4-6. pp. 319-322.
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Fionov A. S., Lund A., Chen W., Rozhkova N. N., Buyanova I. A., Emelyanova G. I., Gorlenko L. E., Golubina E. V., Lokteva E. S., Ōsawa E., Lunin V. V. Paramagnetic centers in detonation nanodiamonds studied by CW and pulse EPR // Chemical Physics Letters. 2010. Vol. 493. No. 4-6. pp. 319-322.
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TY - JOUR
DO - 10.1016/j.cplett.2010.05.050
UR - https://doi.org/10.1016/j.cplett.2010.05.050
TI - Paramagnetic centers in detonation nanodiamonds studied by CW and pulse EPR
T2 - Chemical Physics Letters
AU - Fionov, Alexander Sergeevich
AU - Lund, Anders
AU - Chen, Weimin
AU - Rozhkova, N. N.
AU - Buyanova, Irina A
AU - Emelyanova, G I
AU - Gorlenko, L E
AU - Golubina, Elena V
AU - Lokteva, Ekaterina S
AU - Ōsawa, E.
AU - Lunin, V. V.
PY - 2010
DA - 2010/06/01
PB - Elsevier
SP - 319-322
IS - 4-6
VL - 493
SN - 0009-2614
SN - 1873-4448
ER -
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@article{2010_Fionov,
author = {Alexander Sergeevich Fionov and Anders Lund and Weimin Chen and N. N. Rozhkova and Irina A Buyanova and G I Emelyanova and L E Gorlenko and Elena V Golubina and Ekaterina S Lokteva and E. Ōsawa and V. V. Lunin},
title = {Paramagnetic centers in detonation nanodiamonds studied by CW and pulse EPR},
journal = {Chemical Physics Letters},
year = {2010},
volume = {493},
publisher = {Elsevier},
month = {jun},
url = {https://doi.org/10.1016/j.cplett.2010.05.050},
number = {4-6},
pages = {319--322},
doi = {10.1016/j.cplett.2010.05.050}
}
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MLA
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Fionov, Alexander Sergeevich, et al. “Paramagnetic centers in detonation nanodiamonds studied by CW and pulse EPR.” Chemical Physics Letters, vol. 493, no. 4-6, Jun. 2010, pp. 319-322. https://doi.org/10.1016/j.cplett.2010.05.050.
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