Ultradispersed diamond as an excellent support for Pd and Au nanoparticle based catalysts for hydrodechlorination and CO oxidation
Тип публикации: Journal Article
Дата публикации: 2011-07-01
scimago Q1
wos Q1
БС1
SJR: 0.792
CiteScore: 7.0
Impact factor: 5.1
ISSN: 09259635, 18790062
Materials Chemistry
General Chemistry
Electronic, Optical and Magnetic Materials
Electrical and Electronic Engineering
Mechanical Engineering
Краткое описание
The present study is aimed at the investigation of the catalytic performance of Pd or Au supported on ultradispersed diamond (UDD) catalysts in reductive and oxidative conditions. Very high catalytic activity of Pd or Au supported on ultradispersed diamond (UDD) was observed, in hydrodechlorination and CO oxidation, respectively. Specifically, Pd/UDD shows remarkable selectivity in the hydrodechlorination of 1,3,5-trichlorobenzene (benzene was the main product already at 30% TCB conversion and became the only product after 30 minutes of the reaction), substantially exceeding the performance of Pd supported on activated carbon and commercial 5% Pd/C references. It is proposed that this behavior is linked to the O-containing functional groups at the UDD surface, as detected via IR and EDX/SEM mapping, combined with a very small (6–7 nm by XRD) particle size of UDD support.
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Golubina E. V. et al. Ultradispersed diamond as an excellent support for Pd and Au nanoparticle based catalysts for hydrodechlorination and CO oxidation // Diamond and Related Materials. 2011. Vol. 20. No. 7. pp. 960-964.
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Golubina E. V., Lokteva E. S., Majouga A. G., Lobanov M. V., Lunin V. V. Ultradispersed diamond as an excellent support for Pd and Au nanoparticle based catalysts for hydrodechlorination and CO oxidation // Diamond and Related Materials. 2011. Vol. 20. No. 7. pp. 960-964.
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TY - JOUR
DO - 10.1016/j.diamond.2011.05.020
UR - https://doi.org/10.1016/j.diamond.2011.05.020
TI - Ultradispersed diamond as an excellent support for Pd and Au nanoparticle based catalysts for hydrodechlorination and CO oxidation
T2 - Diamond and Related Materials
AU - Golubina, Elena V
AU - Lokteva, Ekaterina S
AU - Majouga, Alexander G.
AU - Lobanov, M. V.
AU - Lunin, V. V.
PY - 2011
DA - 2011/07/01
PB - Elsevier
SP - 960-964
IS - 7
VL - 20
SN - 0925-9635
SN - 1879-0062
ER -
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BibTex (до 50 авторов)
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@article{2011_Golubina,
author = {Elena V Golubina and Ekaterina S Lokteva and Alexander G. Majouga and M. V. Lobanov and V. V. Lunin},
title = {Ultradispersed diamond as an excellent support for Pd and Au nanoparticle based catalysts for hydrodechlorination and CO oxidation},
journal = {Diamond and Related Materials},
year = {2011},
volume = {20},
publisher = {Elsevier},
month = {jul},
url = {https://doi.org/10.1016/j.diamond.2011.05.020},
number = {7},
pages = {960--964},
doi = {10.1016/j.diamond.2011.05.020}
}
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MLA
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Golubina, Elena V., et al. “Ultradispersed diamond as an excellent support for Pd and Au nanoparticle based catalysts for hydrodechlorination and CO oxidation.” Diamond and Related Materials, vol. 20, no. 7, Jul. 2011, pp. 960-964. https://doi.org/10.1016/j.diamond.2011.05.020.
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