Infrared absorption study of surface functional groups providing chemical modification of nanodiamonds by divalent copper ion complexes
Publication type: Journal Article
Publication date: 2011-08-01
scimago Q1
wos Q1
SJR: 0.792
CiteScore: 7.0
Impact factor: 5.1
ISSN: 09259635, 18790062
Materials Chemistry
General Chemistry
Electronic, Optical and Magnetic Materials
Electrical and Electronic Engineering
Mechanical Engineering
Abstract
Infrared (IR) absorption data evidence the presence of multiple carboxyl and anhydride groups together with hydroxyl and C(sp3)–H groups in the dried copper-modified detonation nanodiamonds (DND). Insignificant differences in IR spectra of initially purified and copper-modified nanodiamonds indicate that in the ion exchange process Cu2+ ions substitute protons just in a small fraction of the entire amount of carboxyl groups on the DND surface. Surface anhydride groups appear as the result of mutual conversion of the neighboring carboxyl groups into the anhydride ones. The observation of specific shape of IR absorption spectrum of DND is a good practical rule for primary selection of detonation nanodiamonds with oxygen-containing functional groups well suitable for targeted surface modification by double-charged metal ions.
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Total citations:
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Citations from 2024:
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GOST
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Osipov V. et al. Infrared absorption study of surface functional groups providing chemical modification of nanodiamonds by divalent copper ion complexes // Diamond and Related Materials. 2011. Vol. 20. No. 8. pp. 1234-1238.
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Osipov V., Aleksenskiy A. E., Shames A. I., Panich A., Shestakov M. S., Vul' A. Infrared absorption study of surface functional groups providing chemical modification of nanodiamonds by divalent copper ion complexes // Diamond and Related Materials. 2011. Vol. 20. No. 8. pp. 1234-1238.
Cite this
RIS
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TY - JOUR
DO - 10.1016/j.diamond.2011.07.008
UR - https://doi.org/10.1016/j.diamond.2011.07.008
TI - Infrared absorption study of surface functional groups providing chemical modification of nanodiamonds by divalent copper ion complexes
T2 - Diamond and Related Materials
AU - Osipov, Vladimir
AU - Aleksenskiy, A. E.
AU - Shames, Alexander I.
AU - Panich, A.M.
AU - Shestakov, M S
AU - Vul', A.Ya.
PY - 2011
DA - 2011/08/01
PB - Elsevier
SP - 1234-1238
IS - 8
VL - 20
SN - 0925-9635
SN - 1879-0062
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2011_Osipov,
author = {Vladimir Osipov and A. E. Aleksenskiy and Alexander I. Shames and A.M. Panich and M S Shestakov and A.Ya. Vul'},
title = {Infrared absorption study of surface functional groups providing chemical modification of nanodiamonds by divalent copper ion complexes},
journal = {Diamond and Related Materials},
year = {2011},
volume = {20},
publisher = {Elsevier},
month = {aug},
url = {https://doi.org/10.1016/j.diamond.2011.07.008},
number = {8},
pages = {1234--1238},
doi = {10.1016/j.diamond.2011.07.008}
}
Cite this
MLA
Copy
Osipov, Vladimir, et al. “Infrared absorption study of surface functional groups providing chemical modification of nanodiamonds by divalent copper ion complexes.” Diamond and Related Materials, vol. 20, no. 8, Aug. 2011, pp. 1234-1238. https://doi.org/10.1016/j.diamond.2011.07.008.