volume 166 pages 307-313

Triphenylamine-functionalized iridium(III) complexes for near-infrared phosphorescent organic light emitting diodes

Publication typeJournal Article
Publication date2019-07-01
scimago Q2
wos Q1
SJR0.680
CiteScore8.5
Impact factor4.2
ISSN01437208, 18733743
General Chemical Engineering
Process Chemistry and Technology
Abstract
With the aim of enhancing the efficiency of near infrared (NIR) organic light-emitting devices (OLEDs), two new triphenylamine-functionalized NIR iridium(III) complexes by covalently attaching the functional moieties (tBu and F) complexes (tBuTPA-BTz-Iq)2Irpic and (FTPA-BTz-Iq)2Irpic were designed and synthesized (TPA = triphenylamine; BTz = benzotriazole; Iq = isoquinoline). It was found that compared to their parent iridium complex (TPA-BTz-Iq)2Irpic, the addition of either butyl or fluorine groups into the ligand play an important role in improving the optophysical and electroluminescent characteristics. In solution-processed phosphorescent OLEDs, the (tBuTPA-BTz-Iq)2Irpic-based devices achieved a maximum external quantum efficiency (EQEmax) of 0.66% at 716 nm, while the (FTPA-BTz-Iq)2Irpic-based devices achieved an EQEmax of 0.48% at 710 nm. The EQEmax level is 2.28 or 1.65 times higher than that in the (TPA-BTz-Iq)2Irpic-based devices (0.29% at 712 nm), respectively.
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GOST |
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GOST Copy
Yu J. et al. Triphenylamine-functionalized iridium(III) complexes for near-infrared phosphorescent organic light emitting diodes // Dyes and Pigments. 2019. Vol. 166. pp. 307-313.
GOST all authors (up to 50) Copy
Yu J., Xu C., Meng F., Tan H., Li M., Zhu W. Triphenylamine-functionalized iridium(III) complexes for near-infrared phosphorescent organic light emitting diodes // Dyes and Pigments. 2019. Vol. 166. pp. 307-313.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.dyepig.2019.03.047
UR - https://doi.org/10.1016/j.dyepig.2019.03.047
TI - Triphenylamine-functionalized iridium(III) complexes for near-infrared phosphorescent organic light emitting diodes
T2 - Dyes and Pigments
AU - Yu, Junting
AU - Xu, Chao
AU - Meng, Fanyuan
AU - Tan, Hua
AU - Li, Maoqiu
AU - Zhu, Weiguo
PY - 2019
DA - 2019/07/01
PB - Elsevier
SP - 307-313
VL - 166
SN - 0143-7208
SN - 1873-3743
ER -
BibTex
Cite this
BibTex (up to 50 authors) Copy
@article{2019_Yu,
author = {Junting Yu and Chao Xu and Fanyuan Meng and Hua Tan and Maoqiu Li and Weiguo Zhu},
title = {Triphenylamine-functionalized iridium(III) complexes for near-infrared phosphorescent organic light emitting diodes},
journal = {Dyes and Pigments},
year = {2019},
volume = {166},
publisher = {Elsevier},
month = {jul},
url = {https://doi.org/10.1016/j.dyepig.2019.03.047},
pages = {307--313},
doi = {10.1016/j.dyepig.2019.03.047}
}