Triphenylamine-functionalized iridium(III) complexes for near-infrared phosphorescent organic light emitting diodes
Publication type: Journal Article
Publication date: 2019-07-01
scimago Q2
wos Q1
SJR: 0.680
CiteScore: 8.5
Impact factor: 4.2
ISSN: 01437208, 18733743
General Chemical Engineering
Process Chemistry and Technology
Abstract
With the aim of enhancing the efficiency of near infrared (NIR) organic light-emitting devices (OLEDs), two new triphenylamine-functionalized NIR iridium(III) complexes by covalently attaching the functional moieties (tBu and F) complexes (tBuTPA-BTz-Iq)2Irpic and (FTPA-BTz-Iq)2Irpic were designed and synthesized (TPA = triphenylamine; BTz = benzotriazole; Iq = isoquinoline). It was found that compared to their parent iridium complex (TPA-BTz-Iq)2Irpic, the addition of either butyl or fluorine groups into the ligand play an important role in improving the optophysical and electroluminescent characteristics. In solution-processed phosphorescent OLEDs, the (tBuTPA-BTz-Iq)2Irpic-based devices achieved a maximum external quantum efficiency (EQEmax) of 0.66% at 716 nm, while the (FTPA-BTz-Iq)2Irpic-based devices achieved an EQEmax of 0.48% at 710 nm. The EQEmax level is 2.28 or 1.65 times higher than that in the (TPA-BTz-Iq)2Irpic-based devices (0.29% at 712 nm), respectively.
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GOST
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Yu J. et al. Triphenylamine-functionalized iridium(III) complexes for near-infrared phosphorescent organic light emitting diodes // Dyes and Pigments. 2019. Vol. 166. pp. 307-313.
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Yu J., Xu C., Meng F., Tan H., Li M., Zhu W. Triphenylamine-functionalized iridium(III) complexes for near-infrared phosphorescent organic light emitting diodes // Dyes and Pigments. 2019. Vol. 166. pp. 307-313.
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TY - JOUR
DO - 10.1016/j.dyepig.2019.03.047
UR - https://doi.org/10.1016/j.dyepig.2019.03.047
TI - Triphenylamine-functionalized iridium(III) complexes for near-infrared phosphorescent organic light emitting diodes
T2 - Dyes and Pigments
AU - Yu, Junting
AU - Xu, Chao
AU - Meng, Fanyuan
AU - Tan, Hua
AU - Li, Maoqiu
AU - Zhu, Weiguo
PY - 2019
DA - 2019/07/01
PB - Elsevier
SP - 307-313
VL - 166
SN - 0143-7208
SN - 1873-3743
ER -
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BibTex (up to 50 authors)
Copy
@article{2019_Yu,
author = {Junting Yu and Chao Xu and Fanyuan Meng and Hua Tan and Maoqiu Li and Weiguo Zhu},
title = {Triphenylamine-functionalized iridium(III) complexes for near-infrared phosphorescent organic light emitting diodes},
journal = {Dyes and Pigments},
year = {2019},
volume = {166},
publisher = {Elsevier},
month = {jul},
url = {https://doi.org/10.1016/j.dyepig.2019.03.047},
pages = {307--313},
doi = {10.1016/j.dyepig.2019.03.047}
}