Open Access

Electrochemistry Communications

, том 9 , издание 9 , страницы 2364-2369

Electrochemical generation of solvated electrons from nanostructured carbon

Тип публикации: Journal Article

Дата публикации: 2007-09-01

Elsevier

Electrochemistry Communications

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SJR: 1.025

CiteScore: 7.9

Impact factor: 4.2

ISSN: 13882481, 18731902

DOI: 10.1016/j.elecom.2007.07.004

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Electrochemistry

Краткое описание

Voltammograms for electrodes fabricated of nanostructured carbon of various morphology (nanotube paper, columnar and filament structures) in hexamethylphosphoric triamide (HMPA) solution have been obtained and analysed. Intensive dark-blue coloration near cathode surface at potentials as low as E ∼ −1.2 V (s.c.e.) has been observed. An ESR (electron spin resonance) spectrum of this frozen dark-blue solution was recorded. This spectrum coincides with one of free electrons. Experimental proofs of the existence of electron emission into electrolytic solutions at moderate cathodic potentials are present for all electrodes. This effect is established to be connected with the presence of atomically sharp areas on the electrode surfaces.

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Journal of Electroanalytical Chemistry	Journal of Electroanalytical Chemistry, 5, 21.74% Journal of Electroanalytical Chemistry 5 публикаций, 21.74%
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Krivenko A. G., Komarova N. S., Piven N. P. Electrochemical generation of solvated electrons from nanostructured carbon // Electrochemistry Communications. 2007. Vol. 9. No. 9. pp. 2364-2369.

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Krivenko A. G., Komarova N. S., Piven N. P. Electrochemical generation of solvated electrons from nanostructured carbon // Electrochemistry Communications. 2007. Vol. 9. No. 9. pp. 2364-2369.

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TY - JOUR

DO - 10.1016/j.elecom.2007.07.004

UR - https://doi.org/10.1016/j.elecom.2007.07.004

TI - Electrochemical generation of solvated electrons from nanostructured carbon

T2 - Electrochemistry Communications

AU - Krivenko, Alexander G

AU - Komarova, Nataly S

AU - Piven, Natalia P

PY - 2007

DA - 2007/09/01

PB - Elsevier

SP - 2364-2369

IS - 9

VL - 9

SN - 1388-2481

SN - 1873-1902

ER -

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@article{2007_Krivenko,

author = {Alexander G Krivenko and Nataly S Komarova and Natalia P Piven},

title = {Electrochemical generation of solvated electrons from nanostructured carbon},

journal = {Electrochemistry Communications},

year = {2007},

volume = {9},

publisher = {Elsevier},

month = {sep},

url = {https://doi.org/10.1016/j.elecom.2007.07.004},

number = {9},

pages = {2364--2369},

doi = {10.1016/j.elecom.2007.07.004}

}

MLA

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Krivenko, Alexander G., et al. “Electrochemical generation of solvated electrons from nanostructured carbon.” Electrochemistry Communications, vol. 9, no. 9, Sep. 2007, pp. 2364-2369. https://doi.org/10.1016/j.elecom.2007.07.004.