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Zwitterionic form of Ugi amine H-phosphinic acid: Structure and electrochemical properties
Publication type: Journal Article
Publication date: 2021-05-01
scimago Q2
wos Q2
SJR: 1.025
CiteScore: 7.9
Impact factor: 4.2
ISSN: 13882481, 18731902
Electrochemistry
Abstract
Ugi amine H-phosphinic acid was prepared by hydrolysis of 1-dichlorophosphanyl-2-N,N-dimethylaminomethylferrocene (1). The formation of the zwitterionic form of Ugi amine H-phosphinic acid (2) was clearly demonstrated by NMR, X-ray single crystal diffraction studies and electrochemical measurements. It was shown for the first time that Ugi amine H-phosphinic acid, unlike other monophosphinates reported in the literature, does not show double oxidation peaks, which clearly indicates the presence of a single form in solution. It is shown that the oxidative potential of 2 is more positive than that of other monophosphinates, since in solution the substance exists completely in the zwitterionic form.
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Khrizanforov M. et al. Zwitterionic form of Ugi amine H-phosphinic acid: Structure and electrochemical properties // Electrochemistry Communications. 2021. Vol. 126. p. 107019.
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Khrizanforov M., Shekurov R. P., Zagidullin A. A., Gerasimova T. I., Ivshin K. A., Kataeva O., Miluykov V. Zwitterionic form of Ugi amine H-phosphinic acid: Structure and electrochemical properties // Electrochemistry Communications. 2021. Vol. 126. p. 107019.
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TY - JOUR
DO - 10.1016/j.elecom.2021.107019
UR - https://doi.org/10.1016/j.elecom.2021.107019
TI - Zwitterionic form of Ugi amine H-phosphinic acid: Structure and electrochemical properties
T2 - Electrochemistry Communications
AU - Khrizanforov, Mikhail
AU - Shekurov, Ruslan P
AU - Zagidullin, Almaz A
AU - Gerasimova, Tatiana I.
AU - Ivshin, Kamil A
AU - Kataeva, O.N.
AU - Miluykov, Vasili
PY - 2021
DA - 2021/05/01
PB - Elsevier
SP - 107019
VL - 126
SN - 1388-2481
SN - 1873-1902
ER -
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@article{2021_Khrizanforov,
author = {Mikhail Khrizanforov and Ruslan P Shekurov and Almaz A Zagidullin and Tatiana I. Gerasimova and Kamil A Ivshin and O.N. Kataeva and Vasili Miluykov},
title = {Zwitterionic form of Ugi amine H-phosphinic acid: Structure and electrochemical properties},
journal = {Electrochemistry Communications},
year = {2021},
volume = {126},
publisher = {Elsevier},
month = {may},
url = {https://doi.org/10.1016/j.elecom.2021.107019},
pages = {107019},
doi = {10.1016/j.elecom.2021.107019}
}
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