Electrochimica Acta, volume 49, issue 16, pages 2581-2589
Ionic conduction in P(VDF-HFP)/PVDF–(PC + DEC)–LiClO 4 polymer gel electrolytes
Publication type: Journal Article
Publication date: 2004-07-01
General Chemical Engineering
Electrochemistry
Abstract
Gel polymer electrolytes composed of poly(vinylidene fluoride-hexafluoropropylene) copolymer, poly(vinylidene fluoride) polymer, PC+DEC as plasticizer and LiClO4 as salt have been synthesized by solvent casting technique with varying the plasticizer-salt concentration ratio systematically. Complex impedance spectroscopy has been carried out to investigate ionic conduction in P(VDF-HFP)–(PC+DEC)–LiClO4 and PVDF–(PC+DEC)–LiClO4 electrolyte systems. Transport number measurements have been made by Wagner’s polarization technique. With all other parameters same, P(VDF-HFP) electrolytes exhibit higher ionic conductivity and transport number as compared to PVDF based electrolytes which could be attributed to higher degree of amorphicity in the P(VDF-HFP) system. XRD and FTIR studies have been conducted to investigate the structural and complexation in the polymer gel electrolytes. Microstructural studies by SEM exhibit higher amorphicity and solvent retention capability for P(VDF-HFP)–(PC+DEC)–LiClO4 system than those of PVDF–(PC+DEC)–LiClO4 system.
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Saikia D., Kumar A. Ionic conduction in P(VDF-HFP)/PVDF–(PC + DEC)–LiClO 4 polymer gel electrolytes // Electrochimica Acta. 2004. Vol. 49. No. 16. pp. 2581-2589.
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Saikia D., Kumar A. Ionic conduction in P(VDF-HFP)/PVDF–(PC + DEC)–LiClO 4 polymer gel electrolytes // Electrochimica Acta. 2004. Vol. 49. No. 16. pp. 2581-2589.
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TY - JOUR
DO - 10.1016/j.electacta.2004.01.029
UR - https://doi.org/10.1016/j.electacta.2004.01.029
TI - Ionic conduction in P(VDF-HFP)/PVDF–(PC + DEC)–LiClO 4 polymer gel electrolytes
T2 - Electrochimica Acta
AU - Saikia, D.
AU - Kumar, Arun
PY - 2004
DA - 2004/07/01 00:00:00
PB - Elsevier
SP - 2581-2589
IS - 16
VL - 49
SN - 0013-4686
ER -
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@article{2004_Saikia,
author = {D. Saikia and Arun Kumar},
title = {Ionic conduction in P(VDF-HFP)/PVDF–(PC + DEC)–LiClO 4 polymer gel electrolytes},
journal = {Electrochimica Acta},
year = {2004},
volume = {49},
publisher = {Elsevier},
month = {jul},
url = {https://doi.org/10.1016/j.electacta.2004.01.029},
number = {16},
pages = {2581--2589},
doi = {10.1016/j.electacta.2004.01.029}
}
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MLA
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Saikia, D., and Arun Kumar. “Ionic conduction in P(VDF-HFP)/PVDF–(PC + DEC)–LiClO 4 polymer gel electrolytes.” Electrochimica Acta, vol. 49, no. 16, Jul. 2004, pp. 2581-2589. https://doi.org/10.1016/j.electacta.2004.01.029.
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